6969-90-0Relevant articles and documents
Synthesis and reactions of silylcarbamates with bulky substituents
Moertl, M.,Knausz, D.,Kolos, Zs.,Szakacs, L.,Csakvari, B.
, p. 183 - 186 (1994)
New silylcarbamates containing bulky substituents were synthesized in order to study their reactivity with nucleophilic agents as lactones and chloroformates.We suggest a mechanism for these reactions.Key words: Silicon
Iron(II)/Persulfate Mediated Newman-Kwart Rearrangement
Gendron, Thibault,Pereira, Raul,Abdi, Hafsa Y.,Witney, Timothy H.,?rstad, Erik
supporting information, p. 274 - 278 (2020/01/02)
Herein, we report that iron(II)/ammonium persulfate in aqueous acetonitrile mediates the Newman-Kwart rearrangement of O-aryl carbamothioates. Electron-rich substrates react rapidly under moderate heating to afford the rearranged products in excellent yie
Pd(II) catalyzed ortho C-H iodination of phenylcarbamates at room temperature using cyclic hypervalent iodine reagents
Sun, Xiuyun,Yao, Xia,Zhang, Chao,Rao, Yu
supporting information, p. 10014 - 10017 (2015/06/22)
A novel approach to access ortho iodinated phenols using cyclic hypervalent iodine reagents through palladium(II) catalyzed C-H activation has been developed through weak coordination. The reaction showed excellent regioselectivity, reactivity and good functional group tolerance. A unique mechanism was proposed.