55682-98-9Relevant academic research and scientific papers
Addition of CCl4 to olefins catalyzed by chromium and ruthenium complexes: The influence of water as a nucleophilic additive
Khusnutdinov,Schadneva,Oshnyakova,Dzhemilev
experimental part, p. 331 - 338 (2010/06/16)
The feasibility of the addition of CCl4 to linear and cyclic olefins and dienes in the presence of chromium and ruthenium complexes was established. The influence of water as a nucleophilic additive and the influence of the olefin nature, the c
Reactions of α-haloallyllithium derivatives with carbon, silicon, tin or boron halides and carbonyl compounds
Julia, Marc,Verpeaux, Jean-Noel,Zahneisen, Thomas
, p. 539 - 554 (2007/10/02)
A series of allylic halides have been converted into their α-carbanions with strong lithium bases, using different techniques.These have been compared in their reaction with various electrophiles leading to functionally substituted allyl derivatives.The influence of the counterion on the regio- and stereoselectivity has been investigated. allylic halides / α-halocarbanions / allylsilanes / allyltin derivatives / α-chlorohydrins / vinylepoxides / diastereoselectivity
Influence on Insecticidal Activity of the 3-(3,4-Methylenedioxyphenyl) Group in the 1,4-Benzodioxanyl Moiety of Haedoxan
Yamauchi, Satoshi,Taniguchi, Eiji
, p. 1744 - 1750 (2007/10/02)
The influence on the insecticidal activity of haedoxan A of its 3-(3,4-methylenedioxyphenyl) group in the 1,4-benzodioxanyl moiety was examined with two (+/-)-(1S*,2R*,5R*,6S*)-6--2-(2,6-dimethoxyphenoxy)-1-hydroxy-3,7-dioxabicyclooctanes.Replacement of the methylenedioxyphenyl group of haedoxan by methyl and n-butyl group resulted in a large decrease in the activity, indicating the importance of the 3-aryl group for the potent insecticidal activity of haedoxan.
ETUDE DE L'ALKYLATION D'ORGANOLITHIENS ALLYLIQUES MONOCHLORES: SYNTHESE EN UNE ETAPE DE CHLORURES ALLYLIQUES SECONDAIRES OU TERTIAIRES ET/OU DE CHLORURES VINYLIQUES DE CONFIGURATION Z
Mauze, B.,Ongoka, P.,Miginiac, L.
, p. 1 - 8 (2007/10/02)
Chloroallyllithium and gem-chloro(methyl)allyllithium readily react with various alkylating reagents to produce, in a "one-pot" reaction, secundary or tertiary allylic chlorides and/or vinylic chlorides of Z configuration.
α-Haloallyllithium Species. Coupling with Alkyl Bromides
Macdonald, Timothy L.,Narayanan, Amirthalingam B.,O'Dell, Dale E.
, p. 1504 - 1506 (2007/10/02)
The regiospecific α-alkylation of in situ generated α-chloroallyllithium species with primary alkyl bromides and the synthetic utility of the derived secondary allylic chloride intermediates are described.
