5572-94-1

Basic information

• Product Name: 5,5-dimethyl-2-(4-iodophenyl)-1,3,2-dioxaborinane
• Synonyms: 5,5-dimethyl-2-(4-iodophenyl)-1,3,2-dioxaborinane
• CAS NO: 5572-94-1
• Molecular Weight: 315.946
• Mol File: 5572-94-1.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 348.2±25.0 °C(Predicted)
• Density: 1.51±0.1 g/cm3(Predicted)
• CAS DataBase Reference: 5,5-dimethyl-2-(4-iodophenyl)-1,3,2-dioxaborinane(CAS DataBase Reference)
• NIST Chemistry Reference: 5,5-dimethyl-2-(4-iodophenyl)-1,3,2-dioxaborinane(5572-94-1)
• EPA Substance Registry System: 5,5-dimethyl-2-(4-iodophenyl)-1,3,2-dioxaborinane(5572-94-1)

Safety Data

• Hazardous Substances Data: 5572-94-1(Hazardous Substances Data)

Upstream product

• 5122-99-6 4-iodophenylboronic acid 
• 126-30-7 2,2-Dimethyl-1,3-propanediol 
• 624-38-4 para-diiodobenzene 

Downstream Products

• 619-58-9 4-iodobenzoic acid 
• 1244016-74-7 4-(aldehydephenylethynyl)benzene boronic acid neopentyl glycol ester 
• 87350-77-4 N-(4-iodophenyl)morpholine 
• 55376-34-6 1-(4-iodophenyl)piperidine 
• 57702-49-5 N,N-diethyl-4-iodo-aniline 
• 40686-52-0 N-(tert-butyl)-4-iodoaniline 
• 619-44-3 methyl 4-iodobenzoate 
• 1590366-84-9 2-(4-iodophenyl)-6-phenylpyridine 
• 62729-39-9 2-(4-carboxyphenyl)-5,5'-dimethyl-1,3,2-dioxaborinane 
• 153688-91-6 4-iodo-N,N-diisopropylaniline 
• 1308658-12-9 1-(cyclopropylmethyl)-4-iodobenzene 
• 1308658-21-0 1-(6-chlorohexyl)-4-iodobenzene 
• 134321-77-0 1-decyl-4-iodobenzene 
• 1244016-73-6 3-((4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)phenyl)ethynyl)pyridine 

Relevant articles and documents

Gold-Catalyzed Oxidative Biaryl Cross-Coupling of Organometallics

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PH-Responsive N-heterocyclic carbene copper(i) complexes: Syntheses and recoverable applications in the carboxylation of arylboronic esters and benzoxazole with carbon dioxide

A pH-controlled monophasic/biphasic switchable system has been developed as a green and novel strategy for homogeneous catalyst recycling, which has been successfully applied to the Cu-NHC-catalyzed carboxylation of organoboronic esters and benzoxazole with carbon dioxide. Additionally, the present strategy could also be extended to the Ag-NHC-catalyzed carboxylation of terminal alkyne. The tertiary amine-functionalized catalysts could be used for at least four times with a slight loss of activity.

Copper-catalyzed cross-coupling reaction of organoboron compounds with primary alkyl halides and pseudohalides

Non-activated alkyl electrophiles, including alkyl iodides, bromides, tosylates, mesylates, and even chlorides, underwent copper-catalyzed cross-coupling with aryl boron compounds and alkyl 9-BBN reagents (see scheme; 9-BBN=9-borabicyclo[3.3.1]nonane). The reactions proceed with practically useful reactivities and thus complement palladium- and nickel-catalyzed Suzuki-Miyaura coupling reactions of alkyl halides.