55724-31-7Relevant academic research and scientific papers
Synthesis of trimethylsilyl carboxylates by HMDS under solvent-free conditions
Jereb, Marjan,Lakner, Janja
, p. 5713 - 5723 (2016/08/23)
A broad set of structurally different carboxylic acids were transformed into their trimethylsilyl esters with HMDS in a practically completely solvent-free process, while a catalytic amount of iodine was required in some cases. The process has several advantages over the known methods: untreated reactants, air atmosphere, mild and neutral conditions, no evolution of hydrogen halide, no need of an additional base, low amount of waste, completely without chromatography, low consumption of energy, and operational simplicity.
One-pot synthesis of 3-hydroxymaleic anhydrides by cyclization of 1,1-bis(trimethylsilyloxy)ketene acetals with oxalyl chloride
Rotzoll, Sven,Ullah, Ehsan,G?rls, Helmar,Fischer, Christine,Langer, Peter
, p. 2647 - 2656 (2007/10/03)
Functionalized 3-hydroxymaleic anhydrides were prepared by cyclization of 1,1-bis(trimethylsilyloxy)ketene acetals with oxalyl chloride.
AN APPROACH TO BUFADIENOLIDES FROM DEOXYCHOLIC ACID -1. STRATEGY AND SYNTHESIS OF A MODEL BUFADIENOLIDE
Hoppe, Hans Wolfgang,Kaiser, Manfred,Mueller, Dietrich,Welzel, Peter
, p. 2045 - 2058 (2007/10/02)
A new procedure for the conversion of deoxycholic acid (14) to bufadienolde 27 is reported.
