557790-55-3Relevant academic research and scientific papers
Sulfur ylides 12. Optically active keto stabilized sulfur ylide obtained from L-proline: Synthesis and study
Lakeev,Mullagalin,Galin,Maidanova,Abdullin
, p. 2230 - 2233 (2007/10/03)
Optically active keto stabilized sulfur ylide was synthesized from L-proline. The reactions of the ylide with methyl acrylate and methyl vinyl ketone afforded 1,2-disubstituted cyclopropanes. In the case of acrylonitrile, a mixture of 1,2- and 1,1-disubstituted cyclopropanes was obtained. Acylation of the ylide with acetic anhydride gave twice stabilized sulfur ylide.
