557793-06-3

Upstream product

• 2873-29-2 D-glucal triacetate 
• 13265-84-4 D-glucal 
• 165524-85-6 6-O-(benzyl)-D-glucal 
• 124-63-0 methanesulfonyl chloride 
• 557793-05-2 3-O-(tert-butyldimethylsilyl)-6-O-(benzyl)-D-glucal 

Downstream Products

• 557793-04-1 (1R,2R,6R)-2-Benzyloxymethyl-3,7-dioxa-bicyclo[4.1.0]hept-4-ene 
• 825638-49-1 6-O-benzyl-3-deoxy-3-azido-D-gulal 
• 557793-03-0 6-O-(benzyl)-4-O-mesyl-D-glucal 

Relevant academic research and scientific papers

Regio- and stereoselectivity of the addition of O-, S-, N-, and C-nucleophiles to the β vinyl oxirane derived from D-glucal

6-O-Trityl- (1a) and 6-(O-benzyl)-substituted epoxide (1b) derived from D-glucal were examined in their addition reactions with O-, C-, N-, and S-nucleophiles. A 1,4-regio- and β-stereoselective or an anti 1,2-addition pathway is commonly observed dependi

New stereoselective β-C-glycosidation by uncatalyzed 1,4-addition of organolithium reagents to a glycal-derived vinyl oxirane

(Matrix presented) Epoxide 4 is generated in situ from D-glucal-derived hydroxy mesylate 3. Reaction of epoxide 4 with a series of alkyl- and aryllithium reagents affords 2,3-unsaturated β-C-glycosides with excellent 1,4-regioselectivity and complete ster