559-14-8Relevant academic research and scientific papers
Method for preparing 1H,1H,2H-perfluoro-1-octene
-
Paragraph 0036-0054, (2019/04/09)
The invention relates to a method for preparing 1H,1H,2H-perfluoro-1-octene. The method includes carrying out elimination reaction on 2-perfluoro hexyl-1-iodine-ethane under the effect of alkali metalalkoxide to obtain the 1H,1H,2H-perfluoro-1-octene. The 2-perfluoro hexyl-1-iodine-ethane is used as a raw material for the 1H,1H,2H-perfluoro-1-octene. The method has the advantages that the yield of products can be greatly increased by the aid of the method, and the purity of the products can be greatly improved by the aid of the method; the raw material for the 1H,1H,2H-perfluoro-1-octene is low in cost and is easily available, synthetic routes are short, the method is simple and convenient, and reaction conditions are mild; the method is easy to operate and has an excellent industrial application prospect.
Perfluoro tertiary alcohols. III. (Perfluoroalkyl)- and (perfluorooxaalkyl)-trimethylsilanes in the synthesis of perfluorinated tertiary alcohols
Chen, Grace J.,Chen, Loomis S.,Eapen, Kalathil C.,Ward, Wayne E.
, p. 61 - 66 (2007/10/02)
High-molecular weight perfluorinated tertiary alcohols, Rf1,Rf2,Rf3C(OH) f1=n-C8F17, Rf2=CF3, Rf3=n-C6F13; Rf1=(CF3)2CFO(CF2)4, Rf2=CF3, Rf3=n-C6F13; Rf1=C3F7O2CF(CF3), Rf2=CF3, Rf3=n-C6F13; Rf1=n-C8F17, Rf2=CF3O2(CF2)2, Rf3=(CF3)2CFO(CF2)2> (IIIa-d), have been prepared by the reactions of (perfluoroalkyl)- and (perfluorooxaalkyl)-trimethylsilanes (Ia-d) with fluoroketones (IIa-c).Ketones containing a trifluoromethyl group as well as higher molecular weight perfluorinated substituents have been studied under different experimental conditions.The yield of tertiary alcohol is influenced by the solvents, reaction temperatures, type and concentration of metal fluorides, and structures of the fluoroalkyltrimethylsilanes and fluoroketones.The reaction has been extended to carbonyl compounds other than ketones.While a perfluorinated secondary acid fluoride gave good yield of the ketone, no reaction was observed with esters.
