55904-99-9

Upstream product

• 123-19-3 4-heptanone 
• 149-73-5 trimethyl orthoformate 
• 67-56-1 methanol 
• 1430321-33-7 C₁₄H₂₁N₃O 

Downstream Products

• 123-19-3 4-heptanone 
• 515871-66-6 ((4S,5S)-5-{[Bis-(4-propoxy-benzyl)-amino]-methyl}-2,2-dipropyl-[1,3]dioxolan-4-ylmethyl)-bis-(4-propoxy-benzyl)-amine 
• 515871-53-1 (5-{[bis-(4-tert-butyl-benzyl)-amino]-methyl}-2,2-dipropyl-[1,3]dioxolan-4-ylmethyl)-bis-(4-tert-butyl-benzyl)-amine 
• 515871-62-2 ((4S,5S)-5-{[Bis-(4-ethoxy-benzyl)-amino]-methyl}-2,2-dipropyl-[1,3]dioxolan-4-ylmethyl)-bis-(4-ethoxy-benzyl)-amine 
• 515871-50-8 ((4S,5S)-5-{[Bis-(4-isopropyl-benzyl)-amino]-methyl}-2,2-dipropyl-[1,3]dioxolan-4-ylmethyl)-bis-(4-isopropyl-benzyl)-amine 
• 515871-59-7 ((4S,5S)-5-{[Bis-(4-methoxy-benzyl)-amino]-methyl}-2,2-dipropyl-[1,3]dioxolan-4-ylmethyl)-bis-(4-methoxy-benzyl)-amine 
• 515871-46-2 ((4S,5S)-5-{[Bis-(4-methyl-benzyl)-amino]-methyl}-2,2-dipropyl-[1,3]dioxolan-4-ylmethyl)-bis-(4-methyl-benzyl)-amine 
• 515870-78-7 Dibenzyl-{(4S,5S)-5-[(dibenzylamino)-methyl]-2,2-dipropyl-[1,3]dioxolan-4-ylmethyl}-amine 
• 87929-18-8 1-Phenyl-3-propyl-hex-2-en-1-one 
• 36235-27-5 (E)-1-Phenyl-3-propyl-hex-3-en-1-one 
• 904368-96-3 C₂₃H₃₀N₂O₂S 

Relevant academic research and scientific papers

Anodic cleavage of several ketone N-phenylsemicarbazones into methyl N-phenylcarbamate and the corresponding dimethyl acetals

Several ketone N-phenylsemicarbazones were electrooxidized in the presence of potassium iodide and a base using methanol as the solvent to give nearly commensurate amounts of methyl N-phenylcarbamate and the corresponding dimethyl acetals. Continuous evolution of gaseous nitrogen was observed from the anolyte during the electrooxidation. The reactions were carried out under very mild reaction conditions and are presumed to proceed through a four-electron oxidation process, in which the iodide ion plays an important role as an electron carrier.

Catalytic asymmetric epoxidation

A compound and method for producing an enantiomerically enriched epoxide from an olefin using a chiral ketone and an oxidizing agent is disclosed.