55967-10-7Relevant academic research and scientific papers
Photochemical rearrangements of silylcyclopropenes: Cyclopropenes which afford pathways to allenes
Kirms, Mark A.,Salcido, Scott L.,Kirms, Lynn Maruyama
, p. 7979 - 7982 (2007/10/02)
The photochemically induced rearrangments of substituted 3,3-dimethyl-1-(trimethylsilyl) cyclopropenes (1c-f) provide an unusually efficient conversion to the corresponding allenes (2c-f). Evidence supportive of a non-carbenoid mechanism for the rearrange
Photochemistry of Cyclopropene Derivatives. 34. Photocycloaddition Reactions of 2-Alkenyl-Substituted Cyclopropenes
Padwa, Albert,Krumpe, Keith E.,Terry, Lenny W.,Wannamaker, M. Woods
, p. 1635 - 1642 (2007/10/02)
The sensitized irradiation of 2-(4-pentenyl)-substituted cyclopropenes produces tricyclo1,3>octanes by means of novel intramolecular cycloaddition.In dramatic contrast to the photochemical results, thermolysis affords a product co
Photolysis of Organopolysilanes. Photochemical Behavior of Phenylethynyldisilanes
Ishikawa, Mitsuo,Sugisawa, Hiroshi,Fuchikami, Takamasa,Kumada, Makoto,Yamabe, Tokio,et al.
, p. 2872 - 2878 (2007/10/02)
The photolysis of phenylethynylpentamethyldisilane (1) afforded 1,1-dimethyl-2-phenyl-3-trimethylsilyl-1-silacyclopropene (8) and 1,1-dimethyl-3-phenyl-3-trimethylsilyl-1-silapropadiene.The absorption and emission spectra of 1 were measured at 300 and 77
