5599-34-8

Usage

Uses

Used in Organic Synthesis:
Triphenylsilylazide is used as a high-energy intermediate for the preparation of silyl-substituted molecules, facilitating the synthesis of a variety of organic compounds.
Used in Surface Modification:
It is employed as a reagent in the modification of surfaces, enhancing their properties for specific applications.
Used in Polymer Preparation:
Triphenylsilylazide is utilized in the preparation of polymers, contributing to the development of materials with tailored characteristics.
Used in Explosives and Propellants Industry:
Due to its high nitrogen content and energetic properties, triphenylsilylazide is investigated for potential use in the development of explosives and propellants, although its use in this industry requires stringent safety measures.
Used in Research and Development:
In the scientific community, triphenylsilylazide is used for research purposes, particularly in exploring its reactivity and potential applications in various chemical reactions and processes.

InChI:InChI=1/C18H16N3Si/c19-20-21-22(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H/q+1

Upstream product

• 76-86-8 Triphenylsilyl chloride 

Downstream Products

• 108148-61-4 4,4-Dimethyl-3-(triphenylsilyl)-5,5-bis(trimethylsilyl)-1,2,3-triaza-4-sila-1-cyclopenten 
• 108148-65-8 4,4-dimethyl-3-triphenylsilyl-5,5-bis(trimethylsilyl)-1,2,3-triaza-4-germa-1-cyclopentene 
• 108148-52-3 5,5-dimethyl-1,4-bis(triphenylsilyl)-1,2,3,4-tetraaza-5-germa-2-cyclopentene 
• 371161-64-7 HC(CCH₃NC₆H₃(C₃H₇)2)2AlNSi(C₆H₅)3 
• 1447045-34-2 C₃₉H₄₆N₂P₂Si 
• 1402222-83-6 C₄₅H₅₁Cl₂N₃Si₂ 
• 108148-62-5 silyl>(trimethylsilyl)diazomethan 
• 104837-17-4 1,3-Bis-triphenylsilyl-2,2,4,4-tetramethyl-cyclodisilazan 
• 17599-59-6 diphenylmethyleneaminotrimethylsilane 
• 30006-66-7 bis(trimethylsilyl)diazomethane 
• 108148-40-9 5,5-Dimethyl-1,4-bis(triphenylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten 
• 1124-52-3 N-(propan-2-ylidene)aniline 
• 512-63-0 1,1,3,3,5,5-hexaphenylcyclotrisiloxane 
• 59239-74-6 1,2,2,3,4,4-Hexamethyl-5,6,6-triphenyl-[1,3,5,2,4,6]triazatrisilinane 

Relevant academic research and scientific papers

An ESR study on structures of a series of silylnitrenes

Structures of a series of silylnitrenes formed from silyl azides were investigated by means of ESR. γ-Irradiation and photo-illumination of all the silyl azides resulted in the formation of triplet states even for those having two or three Si-N3 groups in a molecule. ESR spectra of the silylnitrenes exhibited a part of the fine structure at around 820 mT. All the silyl azides studied gave nearly identical D-values (ca. 1.5cm-1) and much larger than those in phenylnitrenes. The results suggested that electron spins are localized in the nitrogen p-orbitals to a large extent and was interpreted in terms of a mono-silane linkage of nitrene, -Si-N:, i.e., interrupting spin delocalization.

Compound oxidized styrylphosphine

Homopolymers, copolymers and terpolymers of a styrene based monomer are prepared by: (1) polymerizing at least one oxidized styrylphosphine monomer selected from the group of: (2) polymerizing p-diphenylphosphinestyrene and then oxidizing said polymerized p-diphenylphosphinestyrene monomer with an organoazide selected from the group of (C6 H5)2 P(O)N3, (C6 H5 O)2 P(O)N3, (C6 H5)2 C3 N3 (N3) and C6 H5 C3 N3 (N3)2. Copolymers can also be prepared by copolymerizing styrene with at least one oxidized styrylphosphine monomer selected from the group of: