5606-32-6

Basic information

• Product Name: 6-(piperidin-1-yl)-1,3,5-triazine-2,4-diamine
• Synonyms: 1,3,5-triazine-2,4-diamine, 6-(1-piperidinyl)-
• CAS NO: 5606-32-6
• Molecular Formula: C₈H₁₄N₆
• Molecular Weight: 194.237
• Mol File: 5606-32-6.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 472.2°C at 760 mmHg
• Flash Point: 239.4°C
• Density: 1.331g/cm³
• Vapor Pressure: 4.35E-09mmHg at 25°C
• Refractive Index: 1.659
• CAS DataBase Reference: 6-(piperidin-1-yl)-1,3,5-triazine-2,4-diamine(CAS DataBase Reference)
• NIST Chemistry Reference: 6-(piperidin-1-yl)-1,3,5-triazine-2,4-diamine(5606-32-6)
• EPA Substance Registry System: 6-(piperidin-1-yl)-1,3,5-triazine-2,4-diamine(5606-32-6)

Safety Data

• Hazardous Substances Data: 5606-32-6(Hazardous Substances Data)

Upstream product

• 110-89-4 piperidine 
• 1530-87-6 1-piperidinylcarbonnitrile 
• 127099-85-8 N-Cyanoguanidine 
• 3397-62-4 2-Chloro-4,6-diamino-1,3,5-triazine 

Downstream Products

• 1563186-35-5 1-(4-amino-6-piperidino-[1,3,5]-triazin-2-yl)-3-phenylurea 

Relevant articles and documents

Green synthesis and self-association of 2,4-diamino-1,3,5-triazine derivatives

2,4-Diamino-1,3,5-triazines have been prepared by reaction of dicyandiamide with nitriles under microwave irradiation, a method that can be considered as a green procedure due to the reduction in the use of solvents during synthesis and purification, the short reaction time and the simplicity of the procedure. The structures have been confirmed in solution by NMR spectroscopy. Variable temperature experiments have been used to calculate the free energy of activation for rotation about the amino-triazine bond. The crystal structures of three 2,4-diamino-6-R-1,3,5-triazine derivatives (3a: R = phenyl, 3i: R = 1-piperidino and 3g: R = 1-phenylpyrazol-3-yl) have been determined by X-ray analysis. The N-H...N interactions change from structure to structure, resulting in a variation from pseudo-honeycomb networks to corrugated rosette layers.

CYANOETHYLMELAMINE DERIVATIVES AND PROCESS FOR PRODUCING THE SAME

The present invention relates to a cyanoethylmelamine derivatives of the formula I: {wherein 1 to 5 of the substituents X' to X6represent a cyanoethyl group and at least one remaining group represents a C1-20alkyl group, a C2-20alkenyl group (said alkyl or alkenyl group may optionally have an alicyclic group or a phenyl group in its structure), a C5-6cycloalkyl group or a phenyl group, or two of the substituent groups bonded to the same nitrogen atom together may form an alkylene chain having 2 to 7 carbon atoms, and the remaining substituent or substituents represents a hydrogen atom}. The production of cyanoethylmelamine derivatives can be obtained at high yield by reacting N-substituted melamine derivatives with acrylonitrile or reacting mono- or di-halogeno-N-substituted triazine derivative with aminopropionitrile. The compounds of the formula (I) are useful compounds as intermediates for fine chemicals such as agricultural chemicals, medicines, dye stuffs, paints, etc. and as crosslinking intermediates for resins.

Salts of triazine derivatives with oxygenated acids of phosphorus

Disclosed are salts of triazine derivatives with oxygenated acids of phosphorus having the general formula (I): wherein the radicals R and R1 to R7 and subscript n are as defined in claim 1. Said salts are particularly useful as flame-retardant additives for polymers.