56074-62-5

Upstream product

• 21661-84-7 2,2-di-morpholin-4-yl-1-p-tolyl-ethanone 
• 100-66-3 methoxybenzene 
• 90-96-0 bis(p-methoxyphenyl)methanone 
• 68185-94-4 trimethyl-4-methylbenzoylsilane 
• 77385-77-4 2,2-dianisyl-1-tolylvinyl bromide 
• 28997-00-4 (1H-benzo[d]imidazol-1-yl)(p-tolyl)methanone 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 14062-19-2 p-tolylacetic acid ethyl ester 
• 92241-60-6 4,4'-[2-(p-tolyl)ethene-1,1-diyl]bis(methoxybenzene) 
• 92241-59-3 1,1-dianisyl-2-tolylethanol 
• 104-81-4 4-Methylbenzyl bromide 

Relevant academic research and scientific papers

Novel Deoxygenative Acylation of Diaryl Ketones with Acylsilanes Mediated by Lanthanoid Metals

The reaction of diaryl ketones and benzoyltrimethylsilane is mediated by lanthanoid metals such as ytterbium to give the deoxygenatively acylated product, 1,1-diarylacetophenones in good yields.In the reaction with acetylsilane, the corresponding silyl enol ether was obtained in a moderate yield.

Reductive cross-coupling between N-acylbenzimidazoles and diarylketones promoted by Sm/TiCl4

The reductive cross-coupling reaction between N-acylbenzimidazoles and diarylketones promoted by Sm/TiCl4 was performed in refluxing THF under a nitrogen atmosphere, to give 1,2,2-triaryl ethanones in moderate to good yields.

Solvolytic rearrangements of 2,2-Dianisyl-1-tolylvinyl Bromide and (E)- and (Z)-1,2-Dianisyl-2-tolylvinyl Bromide

The solvolysis of 2,2-dianisyl-1-tolylvinyl bromide (3-Br) in AcOH-AgOAc, AcOH-NaOAc, or 2,2,2-trifluoroethanol (TFE)-2,6-lutidine gave complete rearrangement to (E)- and (Z)-1,2-dianisyl-2-tolylvinyl acetates or 2,2,2-trifluoroethyl ethers, respectively,