Tetrahedron Letters p. 6897 - 6898 (1994)
Update date:2022-08-02
Topics:
Taniguchi, Yuki
Nagafuji, Akihiro
Makioka, Yoshikazu
Takaki, Ken
Fujiwara, Yuzo
The reaction of diaryl ketones and benzoyltrimethylsilane is mediated by lanthanoid metals such as ytterbium to give the deoxygenatively acylated product, 1,1-diarylacetophenones in good yields.In the reaction with acetylsilane, the corresponding silyl enol ether was obtained in a moderate yield.
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