56075-36-6

Upstream product

• 20277-69-4 sodium methansulfinate 
• 106-47-8 4-chloro-aniline 
• 17696-73-0 methylsulfinic acid 
• 2028-74-2 p-chlorobenzenediazonium chloride 

Downstream Products

• 17221-37-3 2-(4-chlorophenyl)furan 
• 42498-40-8 N-tert-butyl-4-chlorobenzamide 
• 71320-77-9 moclobemide 
• 195062-61-4 4-chlorophenylboronic acid pinacol ester 
• 6113-62-8 2-(4-chlorophenyl)benzo[d][1,3,2]dioxaborole 
• 123-09-1 4-chlorophenyl methyl sulfide 
• 1016-82-6 1-benzenesulfinyl-4-chloro-benzene 
• 20608-64-4 p-chlorophenyl p-methylphenyl sulfoxide 
• 108-90-7 chlorobenzene 
• 13122-34-4 1-chloro-4-deuterio-benzene 
• 14064-15-4 (4-chlorophenyl)trimethylstannane 
• 3708-04-1 2-methylsulfonyl-1-phenylethanone 
• 24756-07-8 3-(4-chlorophenylhydrazono)-2,4-pentanedione 
• 40640-46-8 2-(2-(4-chlorophenyl)hydrazono)-5,5-dimethylcyclohexane-1,3-dione 

Relevant academic research and scientific papers

Additive- and Photocatalyst-Free Borylation of Arylazo Sulfones under Visible Light

We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows some advantages such as mild conditions, simple equipment, and wide substrate scope, which gives a complementary protocol for the preparation of arylboronates.

Process for converting substituted arylamine into arylazomethyl sulfone

The invention discloses a method for converting substituted arylamine into arylazomethyl sulfone. The method comprises the following steps of: uniformly mixing arylamine, sodium nitrite and an aqueous tetrafluoroboric acid solution, conducting reacting at 0-5 DEG C for 1-2 hours, and performing filtering to remove water so as to obtain a solid aryldiazonium salt; and uniformly mixing the aryldiazonium salt, sodium methanesulfinate and a solvent, conducting reacting for 8-12 hours at a temperature of 0-5 DEG C, performing filtering to remove insoluble solids, concentrating a filtrate obtained after filtering and carrying out recrystallizing to obtain solid arylazomethyl sulfone. According to the invention, water in the aqueous tetrafluoroboric acid solution is directly used as a reaction solvent in the first step, and 1,2-dichloroethane is used as a solvent in the second step, so the problem of low yield of existing preparation methods for arylazomethyl sulfone can be well improved.

Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones

The visible-light-driven preparation of (hetero)aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo sulfones in the presence of hexaalkyldistannanes. The reaction shows a high efficiency and a wide substrates scope. The resulting crude organotin derivatives can be directly employed in a Stille protocol.

Visible Light-Driven, Photocatalyst-Free Arbuzov-Like Reaction via Arylazo Sulfones

A visible light-induced formation of Aryl-Phosphorous bonds starting from arylazo sulfones and triaryl (or trialkyl)phosphites in the absence of any photoredox catalyst and any additives was developed. This reaction showed a broad substrate scope and afforded (hetero)aryl phosphonates in good yields and in up to the gram scale.