56098-09-0Relevant academic research and scientific papers
Synthesis of peroxide compounds by the BF3-catalyzed reaction of acetals and enol ethers with H2O2
Terent'ev,Kutkin,Platonov,Vorontsov,Antipin,Ogibin,Nikishin
, p. 681 - 687 (2007/10/03)
Aliphatic and alicyclic gem-bis-hydroperoxides and their derivatives, bis(1-hydroperoxycycloalkyl) and bis(1-hydroperoxyalkyl) peroxides, dispiro- and tetraalkyl-1,2,4,5-tetroxanes were synthesized by the reaction of aliphatic and alicyclic acetals and enol ethers with H2O2 in the presence of BF3 in anhydrous Et2O.
A new method for the synthesis of bishydroperoxides based on a reaction of ketals with hydrogen peroxide catalyzed by boron trifluoride complexes
Terent'ev, Alexander O.,Kutkin, Alexander V.,Platonov, Maxim M.,Ogibin, Yuri N.,Nikishin, Gennady I.
, p. 7359 - 7363 (2007/10/03)
A reaction of cycloalkanone, alkanone and alkyl aryl ketone ketals with H2O2 catalyzed by boron trifluoride etherate and boron trifluoride-methanol complexes was studied. A new versatile method for the synthesis of bishydroperoxides and their derivatives, viz. 1,1′ -dihydroperoxyperoxides and 1,2,4,5-tetraoxacyclohexanes, was developed based on this reaction.
