7,8,15,16-Tetraoxadispiro[5.2.5.2]hexadecane, 1,10-dimethyl-

Base Information

• Chemical Name: 7,8,15,16-Tetraoxadispiro[5.2.5.2]hexadecane, 1,10-dimethyl-
• CAS No.: 56098-09-0
• Molecular Formula: C14H24O4
• Molecular Weight: 256.342
• DSSTox Substance ID: DTXSID10431624
• Nikkaji Number: J285.608E
• Mol file: 56098-09-0.mol

Synonyms:56098-09-0;7,8,15,16-Tetraoxadispiro[5.2.5.2]hexadecane, 1,10-dimethyl-;DTXSID10431624;1,10-Dimethyl-7,8,15,16-tetraoxadispiro[5.2.5.2]hexadecane

Chemical Property of 7,8,15,16-Tetraoxadispiro[5.2.5.2]hexadecane, 1,10-dimethyl-

Chemical Property:

• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 256.16745924
• Heavy Atom Count: 18
• Complexity: 266

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1CCCCC12OOC3(CCCCC3C)OO2

Technology Process of 7,8,15,16-Tetraoxadispiro[5.2.5.2]hexadecane, 1,10-dimethyl-

There total 2 articles about 7,8,15,16-Tetraoxadispiro[5.2.5.2]hexadecane, 1,10-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1,1-dimethoxy-2-methylcyclohexane (38574-09-3) → 1,10-dimethyl-8,7,15,16-tetraoxa-dispiro<5,2,5,2>hexadecane (56098-09-0) + 2-methylcyclohexylidene-1,1-bishydroperoxide + bis(1-hydroperoxy-2-methylcyclohexyl) peroxide

Guidance literature:

With boron trifluoride diethyl etherate; dihydrogen peroxide; In diethyl ether; at 20 - 25 ℃;

DOI:10.1016/S0040-4039(03)01844-6

Reference yield: 12.0%

methyl enol ether of 2-methylcyclohexanone (1728-38-7) → 1,10-dimethyl-8,7,15,16-tetraoxa-dispiro<5,2,5,2>hexadecane (56098-09-0) + 2-methylcyclohexylidene-1,1-bishydroperoxide + bis(1-hydroperoxy-2-methylcyclohexyl) peroxide

Guidance literature:

With boron trifluoride diethyl etherate; dihydrogen peroxide; In diethyl ether; at 20 ℃; for 1h;

DOI:10.1023/B:RUCB.0000035657.58776.cc

upstream raw materials:

1,1-dimethoxy-2-methylcyclohexane

methyl enol ether of 2-methylcyclohexanone