56182-25-3

Basic information

• Product Name: 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene
• Synonyms: 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene
• CAS NO: 56182-25-3
• Molecular Weight: 262.015
• Mol File: 56182-25-3.mol

Chemical Properties

• CAS DataBase Reference: 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene(56182-25-3)
• EPA Substance Registry System: 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene(56182-25-3)

Safety Data

• Hazardous Substances Data: 56182-25-3(Hazardous Substances Data)

Upstream product

• 614-80-2 2-(acetylamino)phenol 
• 95-55-6 2-amino-phenol 
• 55000-14-1 2-[(2-methyl-2-propenyl)oxy]benzamine 
• 88-75-5 2-hydroxynitrobenzene 
• 13414-54-5 2-[(2-methyl-2-propenyl)oxy]-1-nitrobenzene 

Relevant articles and documents

Chiral N,N Ligands Enabling Palladium-Catalyzed Enantioselective Intramolecular Heck–Matsuda Carbonylation Reactions by Sequential Migratory and CO Insertions

Unprecedented enantioselective intramolecular Heck carbonylation reactions of arenediazonium salts were enabled by a chiral N,N ligand. This reaction constitutes the first enantioselective Heck carbonylation that proceeds through migratory insertion followed by CO insertion. The enantioenriched functionalized dihydrobenzofurans were obtained in good to high yields and enantiomeric ratios of up to 98:2 under mild and operationally simple reaction conditions.

Radical Carbonylation Mediated by Continuous-Flow Visible-Light Photocatalysis: Access to 2,3-Dihydrobenzofurans

The annulative carbonylation of alkenyl-tethered arenediazonium salts using visible-light photocatalysis in continuous flow is described. The method furnishes a diverse series of novel acetate-functionalized 2,3-dihydrobenzofurans at room temperature and