56182-25-3

Basic information

• Product Name: 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene
• Synonyms: 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene
• CAS NO: 56182-25-3
• Molecular Weight: 262.015
• Mol File: 56182-25-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene(56182-25-3)
• EPA Substance Registry System: 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene(56182-25-3)

Safety Data

• Hazardous Substances Data: 56182-25-3(Hazardous Substances Data)

Upstream product

• 13414-54-5 2-[(2-methyl-2-propenyl)oxy]-1-nitrobenzene 
• 88-75-5 2-hydroxynitrobenzene 
• 614-80-2 2-(acetylamino)phenol 
• 95-55-6 2-amino-phenol 
• 55000-14-1 2-[(2-methyl-2-propenyl)oxy]benzamine 

Relevant articles and documents

Chiral N,N Ligands Enabling Palladium-Catalyzed Enantioselective Intramolecular Heck–Matsuda Carbonylation Reactions by Sequential Migratory and CO Insertions

Unprecedented enantioselective intramolecular Heck carbonylation reactions of arenediazonium salts were enabled by a chiral N,N ligand. This reaction constitutes the first enantioselective Heck carbonylation that proceeds through migratory insertion followed by CO insertion. The enantioenriched functionalized dihydrobenzofurans were obtained in good to high yields and enantiomeric ratios of up to 98:2 under mild and operationally simple reaction conditions.

Synthesis of methyl (E)-4-[2-(2,3-dihydro-3-methyl-3-hydroxymethyl-benzo[b]thien-5-yl)-1-propenyl]be nzoate [(E)-3], methyl (E)-4-[2-(2,3-dihydro-3-methyl-3-hydroxymethyl-5-benzofuranyl)-1-propenyl] benzoate [(E)-4], and methyl (E)-4-[2-(2,3-dihydro-3,3-dimethyl-5-benzofuranyl)-3-hydroxy-1-propenyl]benzoate [(E)-7] as potential metabolites of selected heteroarotinoids with fused five-membered ring

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