5628-27-3Relevant academic research and scientific papers
Synthesis of Bipyridyl-, Viologen-, and Quinone-bridged Porphyrins
Leighton, Philip,Sanders, Jeremy K. M.
, p. 2385 - 2394 (2007/10/02)
Mesoporphyrin-II has been bridged by several 2,2'-hydroxymethyl-substituted 4,4'-bipyridine compounds.N-Methylation of the bipyridine bridge groups yielded viologen-bridged porphyrins which have unusual aggregation and fluorescence properties.An improved route to quinone-bridged porphyrins is also reported.
Quinone-capped Porphyrins: Synthesis and some Chemical Properties
Ganesh, K. Nagappa,Sanders, Jeremy K. M.
, p. 1611 - 1616 (2007/10/02)
The 2,5-bis(hydroxyethyl) and 2,5-bis(hydroxypropyl) derivatives of hydroquinone bis(methoxymethyl) ether have been synthesised and used to 'cap' mesoporphyrin-II.Deprotection, oxidation, and metallation gave the title compounds.Several anomalous reactivi
