56310-22-6Relevant academic research and scientific papers
A study by electron spin resonance spectroscopy of the di-t-butylsilanone radical anion
Davies, Alwyn G.,Neville, Anthony G.
, p. 255 - 263 (1992)
The ESR spectrum of the radical anion of di-t-butylsilanone tBu2Si=O-anionradical, can be observed when t-butoxyl radicals react with di-tert-butylsilanol under basic conditions.The magnitude of the hyperfine coupling to 29Si shows that the radical anion is pyramidal at silicon.
Oxidation of sterically hindered organosilicon hydrides using potassium permanganate
Lickiss, Paul D.,Lucas, Ronan
, p. 229 - 234 (2007/10/03)
The one-pot synthesis of Ph3SiOH, tBu2Si(OH)2, (Me3Si)3CSi(OH)3 and (Me3Si)3CSiMe2OH directly from the corresponding bulky silicon hydrides using KMnO4 is described. The size of the substituents, the silane: KMnO4 stoichiometry, the solvent and the application of ultrasound were all shown to influence the rate of the reactions.
