56363-35-0

Basic information

• Product Name: Benzene, 1-methyl-4-(2-phenylcyclopropyl)-, trans-
• CAS NO: 56363-35-0
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• Mol File: 56363-35-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-(2-phenylcyclopropyl)-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-(2-phenylcyclopropyl)-, trans-(56363-35-0)
• EPA Substance Registry System: Benzene, 1-methyl-4-(2-phenylcyclopropyl)-, trans-(56363-35-0)

Safety Data

• Hazardous Substances Data: 56363-35-0(Hazardous Substances Data)

Upstream product

• 56363-35-0 cis-1-p-Methylphenyl-2-phenylcyclopropan 
• 100-42-5 styrene 
• 104-87-0 4-methyl-benzaldehyde 
• 23304-24-7 p-tolyldiazomethane 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 908094-04-2 phenyldiazomethane 

Downstream Products

• 56363-35-0 1-methyl-4-(2-phenylcyclopropyl)benzene 
• 20821-95-8 5-(4-methylphenyl)-3-phenyl-4,5-dihydroisoxazole 
• 20080-09-5 3-(4-methylphenyl)-5-phenyl-4,5-dihydroisoxazole 

Relevant articles and documents

Iron-catalyzed synthesis of cyclopropanes by in situ generation and decomposition of electronically diversified diazo compounds

The modular synthesis of a variety of trans 1,2-disubstituted cyclopropanes in a safe and user-friendly one-pot iron-catalyzed cyclopropanation reaction is described. Easily synthesized N-nosylhydrazones are used as diazo precursors, allowing the in situ generation of electron-rich diazo compounds under mild reaction conditions and their direct participation in the cyclopropanation reaction.

THE MATRIX EFFECT ON STEREOSELECTIVITY OF OLEFIN CYCLOPROPANATION BY ARYLCARBENE

Temperature studies of addition of phenylcarbene to styrene showed that stereoselectivity changed rather dramatically as the reaction phase changed.