56376-63-7Relevant academic research and scientific papers
A new, modulated, oxidative ring cleavage of α-nitrocycloalkanones by Oxone: Synthesis of α,ω-dicarboxylic acids and α,ω-dicarboxylic acid monomethyl esters
Ballini, Roberto,Curini, Massimo,Epifano, Francesco,Marcotullio, Maria Carla,Rosati, Ornelio
, p. 1049 - 1050 (2007/10/03)
By the appropriate choice of the reaction conditions Oxone produces the ring cleavage of α-nitrocycloalkanones affording good yields of α,ω-dicarboxylic acids and α,ω-dicarboxylic acid monomethyl esters, respectively, regardless the ring size and/or the presence of an alkyl group as substituent.
LIQUID-PHASE OXIDATION OF PHENYLCYCLOALKANES BY MOLECULAR OXYGEN. V. COMPOSITION OF THE ACIDIC PRODUCTS FROM OXIDATION OF PHENYLCYCLOHEXANE.
Velyutin, L.P.,Potekhin, V.M.,Ovchinnikov, V.I.
, p. 862 - 866 (2007/10/02)
The composition of the acidic products from the liquid-phase oxidation of phenylcyclohexane by atmospheric oxygen at atmospheric pressure and 120-140 gradC was established. ω-Benzoylvaleric, glutaric, benzoic, and valeric acids are mainly formed with a small amount of other lower mono- and dicarboxylic acids (C1-C4, C6), α- and β-phenyladipic acids, and phenol; their ratio depends on the degree of conversion of the hydrocarbon.Possible paths for the formation of some of the acids were determined on the basis of the obtained kinetic relationships governing the accumulation of the individual acids.
