56382-53-7Relevant articles and documents
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Jarre,W. et al.
, p. 619 - 623 (1975)
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Donor-acceptor ferrocenyl triazines: Synthesis and properties
Maragani, Ramesh,Misra, Rajneesh
, p. 5399 - 5402 (2013)
A series of star shaped donor-π-acceptor type symmetrical triazine was designed and synthesized by the Pd-catalysed Sonogshira cross coupling reaction. The ferrocenyl moiety with different spacer groups acts as donor and 1,3,5-triazine as acceptor. The photophysical results show intramolecular charge transfer from ferrocene to the 1,3,5-triazine unit. The cyclic voltammetric analysis reveals substantial donor-acceptor interaction. The triazines exhibit good thermal stability with high decomposition temperature.
Method for synthesizing 2, 4, 6-trisubstituted 1, 3, 5-triazine compound from aromatic aldehyde and ammonium iodide
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Paragraph 0117-0120, (2020/08/06)
The invention discloses a method for synthesizing a 2, 4, 6-trisubstituted 1, 3, 5-triazine compound from aromatic aldehyde and ammonium iodide, and belongs to the field of organic synthesis. According to the method, aromatic aldehyde and ammonium iodide undergo a one-pot reaction under the catalytic action of a ferric salt, so that the 2, 4, 6-trisubstituted 1, 3, 5-triazine compound is obtained.According to the present invention, the small molecule aryl aldehyde raw material and the iron salt catalyst are used, such that the cost is low, the reaction conditions are mild, the symmetric 2, 4,6-trisubstituted 1, 3, 5-triazine compound can be highly selectively obtained, and the brand-new synthesis idea is provided for the triazine ring construction.
Sigma-spacer regulated thiophenyl triazine conjugates: Synthesis and crystal, electronic and luminescent properties
Zhu, Zhuangli,Shao, Ersha,Xu, Shan,Sun, Huaming,Zhang, Guofang,Xie, Zunyuan,Zhang, Weiqiang,Gao, Ziwei
, p. 76883 - 76889 (2016/08/30)
A water-accelerated Pd catalyzed Suzuki-Miyaura cross-coupling reaction was developed for the synthesis of thiophenyl triazine conjugates (TTCs). The compounds (2a-2e and 3a-3e) with five σ-spacers were obtained and fully characterized. The X-ray analysis of 2a, 2d, and 3d found that the length of the intermolecular H bond was 3.465(3) ? and the π-π interactions ranged from 3.6538(2)-3.9519(1) ?. Five σ-spacers of TTCs had an effect on their emissions from blue (363 nm) to yellow (530 nm) whilst 2- and 3-thiophenyl chromophores finely tune the emission from 530 to 504 nm. The DFT computation showed the TTCs had low HOMO (-6.8 eV) and LUMO (-2.5 eV) energy and high triplet energy (ET, 2.4 eV). The energy level and gap of TTCs were regularly modulated by the σ-spacer.