565-48-0

Basic information

• Product Name: cis-4-hydroxy-alpha,alpha,4-trimethylcyclohexanemethanol
• Synonyms: cis-4-hydroxy-alpha,alpha,4-trimethylcyclohexanemethanol;(1β)-4β-Hydroxy-α,α,4α-trimethylcyclohexane 1β-methanol;(4β)-p-Menthane-1β,8-diol;4α-Hydroxy-α,α,4β-trimethylcyclohexane-1α-methanol;cis-Terpin;4-p-Menthan-1,8-diol;RBNWAMSGVWEHFP-WAAGHKOSSA-N
• CAS NO: 565-48-0
• Molecular Formula: C₁₀H₂₀O₂
• Molecular Weight: 172.2646
• EINECS: 209-279-5
• Mol File: 565-48-0.mol
• Article Data: 7

Chemical Properties

• Melting Point: 104 °C
• Boiling Point: 265°Cat760mmHg
• Flash Point: 119°C
• Appearance: /
• Density: 1.018g/cm³
• PKA: 15.18±0.29(Predicted)
• CAS DataBase Reference: cis-4-hydroxy-alpha,alpha,4-trimethylcyclohexanemethanol(CAS DataBase Reference)
• NIST Chemistry Reference: cis-4-hydroxy-alpha,alpha,4-trimethylcyclohexanemethanol(565-48-0)
• EPA Substance Registry System: cis-4-hydroxy-alpha,alpha,4-trimethylcyclohexanemethanol(565-48-0)

Safety Data

• Hazardous Substances Data: 565-48-0(Hazardous Substances Data)

Upstream product

• 25570-95-0 1,4-dichloro-trans-p-menthane 
• 98-55-5 terpineol 
• 7785-70-8 (+)-α-pinene 
• 80-56-8 rac-α-pinene 
• 25570-96-1 1,4-dibromo-p-menthane 
• 563-63-3 silver(I) acetate 
• 64-19-7 acetic acid 
• 5114-00-1 trans-p-menthan-8-ol 
• 917-64-6 methyl magnesium iodide 
• 61187-22-2 1-(c-4'-hydroxy-4'-methyl-r-1'-cyclohexyl)ethanone 
• 27621-71-2 1,4-dichloro-p-menthane 
• 64-17-5 ethanol 
• 7664-93-9 sulfuric acid 
• 7732-18-5 water 

Downstream Products

• 20009-20-5 1,8-diacetoxy-p-menthane 
• 99-86-5 1-methyl-4-isopropyl-1,3-cyclohexadiene 
• 1127-33-9 1,8-dibromo-p-menthane 
• 4436-81-1 homoterpenylmethylketone 
• 470-67-7 1,4-cineole 
• 138-86-3 limonene. 
• 68245-39-6 1,8-diacetoxy-trans-p-menthane 
• 59632-85-8 cis-β-terpenyl acetate 
• 20777-47-3 r-1-acetoxy-c-4-p-menth-8⁽⁹⁾-ene 
• 127322-89-8 trans-N,N'-di(chloroacetyl)-p-menthane-1,8-diamine 
• 127322-85-4 cis-N,N'-di(chloroacetyl)-p-menthane-1,8-diamine 
• 112766-74-2 trans-N,N’-dibenzoyl-p-menthane-1,8-diamine 
• 127322-87-6 cis-N,N’-dibenzoyl-p-menthane-1,8-diamine 
• 127322-88-7 trans-N-(2-(4-acetamido-4-methylcyclohexyl)propan-2-yl)acetamide 

Relevant articles and documents

Hydroxylation of Acetoxy-p-menthenes in the Cultured Cells of Nicotiana tabacum. Epoxidation of the Carbon-Carbon Double Bond

The process of the formation of glycols in the biotransformation of 1-acetoxy-p-menth-4(8)-ene and 8-acetoxy-p-menth-1-ene in the cultured cells of Nicotiana tabacum was examined.The formation of the glycols was found to result from epoxidation of the C-C double bond, followed by hydrolysis of the resulting epoxides.

Reaction of platinum complexes with (+)-α-pinene and (+)-limonene. Synthesis, molecular structure, and catalytic activity of dichloro(η 4-[p-mentha-1,8{9}-diene])platinum(II)

The transformations of platinum(II) and platinum(IV) complexes with inner-and outer-sphere ligands by the action of (+)-α-pinene and (+)-limonene were studied. Reduction of the metal complex is the main process whose rate increases in the following outer-sphere ligand series: (Me 2SO)2H+ 3NH+ - +. The reaction of K2PtCl4 with α-pinene gave cis-terpine monohydrate and dichloro-η4- [p-mentha-1,8(9)-diene]platinum(II), and their structure was proved by X-ray analysis. The complex belongs to monoclinic crystal system, the Pt-Cl and Pt-C bonds therein have different lengths, the ClPtCl angle is 85.88°, and the C=C bond plane is orthogonal to the square coordination core. Dichloro-η4-[p-mentha-1,8(9)-diene]-platinum(II) was tested as catalyst in the hydrosilylation of acetophenone with diphenylsilane. Nauka/Interperiodica 2006.

7-Hydroxy-1,8-cineole and 7-Cineolic Acid. Two New Possum Urinary Metabolites

7-Hydroxy-1,8-cineole (3a) and the corresponding carboxylic acid (3b) have been isolated from the urine of brushtail possums (Trichosurus vulpecula: Marsupialia) fed a diet enhanced with 1,8-cineole.Chemical syntheses of these two novel metabolites are described.