112766-74-2Relevant articles and documents
NUCLEOPHILIC ADDITION OF NITRILES TO TERTIARY MONOCYCLIC TERPENES ALCOHOLS
Popova, L. A.,Kozlov, N. G.
, p. 196 - 200 (1987)
Previously unknown secondary amines have been synthesized by the Ritter reaction of p-menthan-8-ol with propio- and benzonitriles.The performance of this reaction with α-terpeneol and benzonitrile led to the formation of a mixxture of N-(p-menth-1-en-8-y1)benzamide and N, N-(p-menth-1,8,diyl)dibenzamide.A transdiamide was also obtained on the reaction of α-terpineol with isovaleronitrile.The use of propionitrile as the nucleophile with α-terpineol led to the formation of 2-ethyl-4,4,8-trimethyl-8-propionamido-3-azabicyclo non-2-ene.