565473-40-7

Upstream product

• 26042-63-7 silver(I) hexafluorophosphate 
• 565473-38-3 [(η5-MeC5H4)Ru(diphenylvinylphosphine)(CO)(Br)] 
• 75-05-8 acetonitrile 

Downstream Products

• 841262-09-7 (C₅H₄(CH₃))Ru(P(C₆H₅)2(C₆H₅PC₆H₅(CH₃)2))(CO)⁽¹⁺⁾*PF₆^(1-)=[(C₆H₇)Ru(P(C₆H₅)2(C₁₄H₁₆P))(CO)][PF₆] 

Relevant academic research and scientific papers

Diphenylvinylphosphine (DPVP) complexes containing the (η5-MeC5H4)Ru(II) moiety: Synthesis, characterization and reactions

The complex [(η5-MeC5H4)Ru(DPVP)2(CH3 CN)]PF6 (4) (DPVP = Ph2PCH=CH2) loses CH3CN under vacuum to produce the phosphaallyl complex [(η5-MeC5H4)Ru(η1-DPVP)( η3-DPVP)]PF6 (6) and reacts with Me3SiC≡CH and PhC≡CH in CH2Cl2-CH3OH solutions to form the methoxymethylcarbene [(η5-MeC5H4)(DPVP)2Ru=C(OCH 3)(CH3)]PF6 (7) and the carbonyl complex [(η5-MeC5H4)Ru(DPVP)2(CO)]PF 6 (8), respectively. In contrast [(η5-MeC5H4)Ru(DPVP)(CO)(CH3CN)] PF6 (15) does not lose CH3CN to form a phosphaallyl complex. The structures of the complexes described herein have been deduced from elemental analyses, infrared spectroscopy, 1H, 13C{1H}, 1H NOE, where appropriate by 31P{1H} NMR spectroscopy and in eight cases by X-ray crystallography.