56641-72-6Relevant academic research and scientific papers
Investigation of the reaction between diphenylphosphine and carbon tetrachloride
Majewski, Piort
, p. 399 - 406 (1998)
The mechanism of diphenyltrichloromethylphosphine (4) formation in the title reaction has been studied. It has been established that the diphenyltrichloromethylphosphine is formed in the multistep reaction sequence (Scheme 1), which involves the intermediacy of chlorodiphenylphosphine (2) and tetraphenyldiphosphine (3). This process is analogous to the formation of dialkyltrichloromethylphosphines in the dialkylphosphine / CCl4 reaction.
SYNTHESIS AND CHEMISTRY OF DIALKYL- AND DIARYLTRICHLOROMETHYLPHOSPHINES
Majewski, Piotr
, p. 185 - 194 (2007/10/02)
Dialkyltrichloromethylphosphines; diphenyltrichloro-methylphosphine; P-chloro-dialkyl-dichloromethylenephosphoranes; P-chloro-diphenyl-dichloromethylenephophorane; phosphonium salt; chlorination; dehydration; condensation.
REACTION OF SECONDARY PHOSPHINES WITH CARBON TETRACHLORIDE. SYNTHESIS OF ALKYLACYLCHLOROPHOSPHINES
Veits, Yu. A.,Neganova, E. G.,Filippov, M. V.,Borisenko, A. A.,Foss, V. L.
, p. 114 - 118 (2007/10/02)
We present a method for the synthesis of hitherto unknown chlorides of alyklacylphosphinic acids by reaction of alkylacylphosphines with carbon tetrachloride in the presence of triethylamine.We have discovered a reaction of chlorides of alkylacylphosphinic acids in which intermolecular migration of an acyl group takes place.
