Investigation of the reaction between diphenylphosphine and carbon tetrachloride

Article abstract of DOI:10.1080/10426509808545480

The mechanism of diphenyltrichloromethylphosphine (4) formation in the title reaction has been studied. It has been established that the diphenyltrichloromethylphosphine is formed in the multistep reaction sequence (Scheme 1), which involves the intermediacy of chlorodiphenylphosphine (2) and tetraphenyldiphosphine (3). This process is analogous to the formation of dialkyltrichloromethylphosphines in the dialkylphosphine / CCl₄ reaction.

Full text of DOI:10.1080/10426509808545480

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Phosphorus, Sulfur, and
Silicon and the Related
Elements
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Investigation of the
Reaction Between
Diphenylphosphine and
Carbon Tetrachloride
Piort Majewski
a Institute of Organic Chemistry, Technical
University , Żwirki 36 90–924 LÓDŹ, POLAND
Published online: 17 Mar 2008.
To cite this article: Piort Majewski (1998) Investigation of the Reaction
Between Diphenylphosphine and Carbon Tetrachloride, Phosphorus,
Sulfur, and Silicon and the Related Elements, 134:1, 399-406, DOI:
10.1080/10426509808545480
To link to this article: http://dx.doi.org/10.1080/10426509808545480
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