56683-56-8

Usage

Uses

Used in Organic Synthesis:
2,3-(4-Methoxycarbonylbenzo)-1,4,7,10,13-pentaoxacyclopentadec-2-ene is used as a building block in organic synthesis for the creation of various complex organic molecules. Its unique structure allows for the formation of new chemical bonds and the synthesis of novel compounds with potential applications in various fields.
Used in Material Science:
In the field of material science, 2,3-(4-Methoxycarbonylbenzo)-1,4,7,10,13-pentaoxacyclopentadec-2-ene is used as a component in the development of new materials with specific properties. Its incorporation into polymers, for example, may lead to materials with enhanced characteristics such as improved stability, reactivity, or selectivity in certain applications.

InChI:InChI=1/C16H22O7/c1-18-16(17)13-2-3-14-15(12-13)23-11-9-21-7-5-19-4-6-20-8-10-22-14/h2-3,12H,4-11H2,1H3

Upstream product

• 67-56-1 methanol 
• 54664-43-6 4'-benzo-15-crown-5-carboxylic acid chloride 
• 56683-55-7 2,3-(4'-carboxybenzo)-1,4,7,10,13-pentaoxacyclopentadeca-2-ene 
• 60835-73-6 benzo-15-crown-5-ether 
• 41757-95-3 2-Acetyl-6,7,9,10,12,13,15,16-octahydro-1,4,7,10,13-pentaoxabenzocyclopentadecene 
• 1037072-53-9 C₁₆H₂₃ClO₇ 

Downstream Products

• 65558-67-0 2-Hydroxymethyl-6,7,9,10,12,13,15,16-octahydro-1,4,7,10,13-pentaoxabenzocyclopentadecene 

Relevant academic research and scientific papers

Combinatorial Evolution of Fast-Conducting Highly Selective K+-Channels via Modularly Tunable Directional Assembly of Crown Ethers

We describe here a modularly tunable molecular strategy for construction and combinatorial optimization of highly efficient K+-selective channels. In our strategy, a highly robust supramolecular H-bonded 1D ensemble was used to order the appended crown ethers in such a way that they roughly stack on top of each other to form a channel for facilitated ion transport across the membrane. Among 15 channels that all prefer K+ over Na+ ions, channel molecule 5F8 shows the most pronounced optimum for K+ while disfavoring all other biologically important cations (e.g., Na+, Ca2+ and Mg2+). With a K+/Na+ selectivity of 9.8 and an EC50 value of 6.2 μM for K+ ion, 5F8 is clearly among the best synthetic potassium channels developed over the past decades.

Syntheses of cis- and trans-dibenzo-30-crown-10 derivatives via regioselective routes and their complexations with paraquat and diquat

(Chemical Equation Presented) cis-Dibenzo-30-crown-10 (cis-DB30C10) diester and trans-dibenzo-30-crown-10 (trans-DB30C10) diester were synthesized regioselectively with reasonable yields. These two isomers were further reduced to cis-dibenzo-30-crown-10 d

Benzo-15-crown-5 Derivatives. Synthesis and Properies as Ion-extraction and Ion-transport Agents

The preparation of some derivatives of benzo-15-crown-5 is described, each containing a carbohydrate moiety attached through either an ester or an ether linkage.The ion-extraction properties into dichloromethane of these and other related benzo-15-crown-5