566905-12-2

Basic information

• Product Name: Methanesulfonic acid, trifluoro-, (3S,5R)-1-oxo-2-(phenylmethyl)-7-(phenylsulfonyl)-3-[2-[(tetrahydro-2H- pyran-2-yl)oxy]ethyl]-2,7-diazaspiro[4.5]dec-9-en-10-yl ester
• CAS NO: 566905-12-2
• Molecular Formula: C29H33F3N2O8S2
• Molecular Weight: 658.717
• Mol File: 566905-12-2.mol

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid, trifluoro-, (3S,5R)-1-oxo-2-(phenylmethyl)-7-(phenylsulfonyl)-3-[2-[(tetrahydro-2H- pyran-2-yl)oxy]ethyl]-2,7-diazaspiro[4.5]dec-9-en-10-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid, trifluoro-, (3S,5R)-1-oxo-2-(phenylmethyl)-7-(phenylsulfonyl)-3-[2-[(tetrahydro-2H- pyran-2-yl)oxy]ethyl]-2,7-diazaspiro[4.5]dec-9-en-10-yl ester(566905-12-2)
• EPA Substance Registry System: Methanesulfonic acid, trifluoro-, (3S,5R)-1-oxo-2-(phenylmethyl)-7-(phenylsulfonyl)-3-[2-[(tetrahydro-2H- pyran-2-yl)oxy]ethyl]-2,7-diazaspiro[4.5]dec-9-en-10-yl ester(566905-12-2)

Safety Data

• Hazardous Substances Data: 566905-12-2(Hazardous Substances Data)

Upstream product

• 566905-10-0 (3S,5R)-2-benzyl-3-(2-hydroxyethyl)-7-(phenylsulfonyl)-2,7-diazaspiro[4.5]decane-1,10-dione 

Downstream Products

• 566905-38-2 bis[3-[4-((3S,5S,10R)-2-(tert-butoxycarbonyl)-1-oxo-7-(phenylsulfonyl)-3-[2-(tetrahydro-2H-pyran-2-yloxy)ethyl]-2,7-diazaspiro[4.5]dec-10-yl)-2-furyl]propyl] carbonate 
• 566905-15-5 tert-butyl (3S,5S,10R)-10-(5-[3-[(tert-butoxycarbonyl)oxy]propyl]-3-furyl)-1-oxo-7-(phenylsulfonyl)-3-[2-(tetrahydro-2H-pyran-2-yloxy)ethyl]-2,7-diazaspiro[4.5]decane-2-carboxylate 
• 566905-23-5 C₃₆H₄₃N₃O₉SSe 
• 566905-16-6 tert-butyl (3S,5S,10R)-1-(acetyloxy)-10-[5-[3-(acetyloxy)propyl]-3-furyl]-7-(phenylsulfonyl)-3-[2-(tetrahydro-2H-pyran-2-yloxy)ethyl]-2,7-diazaspiro[4.5]decane-2-carboxylate 
• 566905-13-3 ethyl 3-(4-[(3S,5S,10R)-2-benzyl-1-oxo-7-(phenylsulfonyl)-3-[2-(tetrahydro-2H-pyran-2-yloxy)ethyl]-2,7-diazaspiro[4.5]dec-10-yl]-2-furyl)propanoate 
• 566905-40-6 tert-butyl (2S,3aS,7aS,10bS)-9-[3-(acetyloxy)propyl]-2-[2-(tetrahydro-2H-pyran-2-yloxy)ethyl]-5-(phenylsulfonyl)-2,3,4,5,6,7,7a,10b-octahydro-1H-furo[3,2:3,4]pyrrolo[3,2:1,5]cyclopenta[1,2-c]pyridine-1-carboxylate 
• 566905-33-7 ethyl 3-(4-[(3S,5S,10RS)-2-benzyl-1-oxo-7-(phenylsulfonyl)-3-[2-(tetrahydro-2H-pyran-2-yloxy)ethyl]-2,7-diazaspiro[4.5]dec-10-yl]-2-furyl)propanoate 
• 566905-14-4 (3S,5S,10R)-2-benzyl-10-[5-(3-hydroxypropyl)-3-furyl]-7-(phenylsulfonyl)-3-[2-(tetrahydro-2H-pyran-2-yl-oxy)ethyl]-2,7-diazaspiro[4.5]decan-1-one 
• 566905-19-9 3-[(2S,3aS,7aS,10bS)-1-(5-hexenoyl)-5-(phenylsulfonyl)-2-vinyl-2,3,4,5,6,7,7a,10b-octahydro-1H-furo[3,2:3,4]pyrrolo[3,2:1,5]cyclopenta[1,2-c]pyridin-9-yl]propyl acetate 
• 566905-34-8 ethyl 3-(4-[(3S,5S,10R)-2-benzyl-1-oxo-7-(phenylsulfonyl)-3-(2-hydroxyethyl)-2,7-diazaspiro[4.5]dec-10-yl]-2-furyl)propanoate 
• 566905-17-7 tert-butyl (2S,3aS,7aS,10bS)-9-[3-(acetyloxy)propyl]-2-2-(hydroxyethyl)-5-(phenylsulfonyl)-2,3,4,5,6,7,7a,10b-octahydro-1H-furo[3,2:3,4]pyrrolo[3,2:1,5]cyclopenta[1,2-c]pyridine-1-carboxylate 
• 566905-37-1 (3S,5S,10R)-10-[5-(3-hydroxypropyl)-3-furyl]-7-(phenylsulfonyl)-3-[2-(tetrahydro-2H-pyran-2-yloxy)ethyl]-2,7-diazaspiro[4.5]decan-1-one 
• 566905-18-8 tert-butyl (2S,3aS,7aS,10bS)-9-[3-(acetyloxy)propyl]-5-(phenylsulfonyl)-2-vinyl-2,3,4,5,6,7,7a,10b-octahydro-1H-furo[3,2:3,4]pyrrolo[3,2:1,5]cyclopenta[1,2-c]pyridine-1-carboxylate 
• 566905-41-7 3-[(2S,3aS,7aS,10bS)-5-(phenylsulfonyl)-2-vinyl-2,3,4,5,6,7,7a,10b-octahydro-1H-furo[3,2:3,4]pyrrolo[3,2:1,5]cyclopenta[1,2-c]pyridin-9-yl]propyl acetate 

Relevant articles and documents

The first total synthesis of nakadomarin A

(-)-Nakadomarin A is a member of manzamine alkaloid isolated from a marine sponge and have a unique hexacyclic structure. The first total synthesis of (+)-nakadomarin A, an enantiomer of natural product, has been accomplished from stereochemically defined 4-oxopiperidin-3-carboxylic acid derivative. The synthesis established the structure of nakadomarin A including absolute configuration. Copyright