56701-13-4Relevant academic research and scientific papers
TMSCFX2(X = Cl, Br) as halofluorocarbene sources for the synthesis of halofluorocyclopropanes
Chen, Dingben,Fan, Zili,Huang, Ling,Gao, Kaili,Xiao, Pan,Ni, Chuanfa,Hu, Jinbo
, p. 319 - 322 (2021/01/25)
TMSCFX2 (X = Cl, Br; TMS = trimethylsilyl) have been developed as halofluorocarbene (CFX, X = Cl, Br) precursors for [2+1] cyclopropanation with alkenes. Structurally diverse halofluorocyclopropanes were obtained in good to excellent yields. It was found
Synthesis of monofluoromethylcyclopropanes from alkenes without using freons: Novel synthesis of chlorofluoromethyl phenyl sulfide and its application in cyclopropanation
Kirihara, Masayuki,Ogata, Tomomi,Itou, Atsushi,Naito, Sayuri,Kishida, Mari,Yamazaki, Kento,Tabata, Hidetsugu,Takahashi, Hideyo
, p. 1377 - 1379 (2013/11/19)
Chlorofluoromethyl phenyl sulfide was prepared from the reaction of chloromethyl phenyl sulfide with Selectfluor. Monofluorocyclopropanation of an alkene was achieved via cyclopropanation using a fluorocarbene derived from the product chlorofluoromethyl phenyl sulfide, followed by oxidation and desulfurization.
