56714-80-8Relevant academic research and scientific papers
Solvent-free and direct C(sp3)-H amination of adamantanes by grinding
Wei, Zhen,Li, Jiarong,Wang, Ning,Zhang, Qi,Shi, Daxin,Sun, Kening
supporting information, p. 1395 - 1400 (2014/02/14)
A facile, direct and environmentally benign conversion of C(sp 3)-H bonds to C(sp3)-N bonds using substoichiometric amount of aprotic superelectrophiles polyhalomethane-AlX3 has been achieved by grinding under solvent-free
Iron(iii) tetrakis(pentafluorophenyl)porpholactone catalyzes nitrogen atom transfer to CC and C-H bonds with organic azides
Liang, Lei,Lv, Hongbin,Yu, Yi,Wang, Peng,Zhang, Jun-Long
supporting information; experimental part, p. 1457 - 1460 (2012/03/22)
We have demonstrated that iron porpholactones could be effective catalysts for nitrogen atom transfer reactions such as aziridination of alkenes and amidation of alkanes using organic azides.
[FeIII(F20-tpp)Cl] Is an effective catalyst for nitrene transfer reactions and animation of saturated hydrocarbons with sulfonyl and aryl azides as nitrogen source under thermal and microwave-assisted conditions
Liu, Yungen,Che, Chi-Ming
experimental part, p. 10494 - 10501 (2010/10/21)
[FeIII(F20-tpp)Cl] (F20tpp = meso- tetrakis(pentafluorophenyl)porphyrinato dianion) is an effective catalyst for imido/nitrene insertion reactions using sulfonyl and aryl azides as nitrogen source. Under thermal conditions, aziridination of aryl and alkyl alkenes (16 examples, 60-95% yields), sulfimidation of sulfides (11 examples, 76-96% yields), allylic amidation/amination of α-methylstyrenes (15 examples, 68-83% yields), and amination of saturated C-H bonds including that of cycloalkanes and adamantane (eight examples, 64-80% yields) can be accomplished by using 2 mol % [FeIII(F20- tpp)Cl] as catalyst. Under microwave irradiation conditions, the reaction time of aziridination (four examples), allylic amination (five examples), sulfimidation (two examples), and amination of saturated C-H bonds (three examples) can be reduced by up to 16fold (24-48 versus 1.5-6 h) without significantly affecting the product yield and substrate conversion.
Adamantylation of nitro-substituted aromatic amines in protic acids
Volkova,Platonova,Tsypin,Polukeev
experimental part, p. 1719 - 1727 (2009/02/06)
Adamantylation of mono-and dinitro-substituted aromatic amines in sulfuric and phosphoric acids and in a mixture of phosphoric and acetic acids gives mainly the corresponding N-adamantyl derivatives. The results of kinetic measurements showed reversible c
Hypobetalipoproteinemic agents. II. Compounds related to 4-(1- adamantyloxy)aniline
Lednicer,Heyd,Emmert,et al.
, p. 69 - 77 (2007/10/06)
While the previously used displacement reaction of sodium 1-adamantyl oxide on 4-fluoronitrobenzene was applicable to the preparation of 4-(1-adamantyloxy) aniline and several related compounds, certain derivatives were not easily accessible by this route
