5676-29-9

Basic information

• Product Name: (1-tert-Butylvinyl)benzene
• Synonyms: (1-tert-Butylvinyl)benzene;3,3-Dimethyl-2-phenyl-1-butene
• CAS NO: 5676-29-9
• Molecular Formula: C₁₂H₁₆
• Molecular Weight: 160.26
• Mol File: 5676-29-9.mol
• Article Data: 26

Chemical Properties

• Boiling Point: 214.9°Cat760mmHg
• Flash Point: 76.9°C
• Appearance: /
• Density: 0.867g/cm³
• Vapor Pressure: 0.223mmHg at 25°C
• Refractive Index: 1.499
• CAS DataBase Reference: (1-tert-Butylvinyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1-tert-Butylvinyl)benzene(5676-29-9)
• EPA Substance Registry System: (1-tert-Butylvinyl)benzene(5676-29-9)

Safety Data

• Hazardous Substances Data: 5676-29-9(Hazardous Substances Data)

Usage

General Description

(1-tert-Butylvinyl)benzene is a chemical compound with the molecular formula C13H18. It is a member of the class of styrenes that contains a tert-butyl group and a vinyl group on the benzene ring. (1-tert-Butylvinyl)benzene is often used in the production of polymers and resins due to its unique structure and reactivity. It is typically used as a monomer in the synthesis of various polymeric materials, such as thermosetting plastics and elastomers. Additionally, it can also be used as a precursor in the synthesis of other valuable chemicals. Overall, (1-tert-Butylvinyl)benzene is an important chemical in the field of polymer chemistry and material science.

InChI:InChI=1/C12H16/c1-10(12(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3

Upstream product

• 75-97-8 3,3-dimethyl-butan-2-one 
• 2117-28-4 bis(trimethylsilyl)methane 
• 938-16-9 2,2-dimethylpropiophenone 
• 2371-91-7 2,3-dimethyl-3-phenylbutan-2-ol 
• 96-09-3 styrene oxide 
• 42044-42-8 3,3-dimethyl-2-phenyl-2-butyl p-nitrobenzoate 
• 1923-01-9 trimethyl(1-phenylvinyl)silane 
• 63034-23-1 C₁₂H₁₇⁽¹⁺⁾ 
• 70712-85-5 1-phenyl-2,2-dimethyl-1-propyl bromide 
• 2181-42-2 trimethylsulphonium iodide 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 558-37-2 tert-butylethylene 
• 71-43-2 benzene 
• 594-19-4 tert.-butyl lithium 

Downstream Products

• 134391-09-6 3-acetyl-5-tert-butyl-2-methyl-5-phenyl-4,5-dihydrofuran 
• 134391-17-6 5-tert-butyl-3-(methoxycarbonyl)-5-phenyl-γ-butyrolactone 
• 134391-16-5 methyl 2-(methoxycarbonyl)-5,5-dimethyl-4-methoxy-4-phenylhexanoate 
• 98-86-2 acetophenone 
• 42805-25-4 3,3-dimethyl-2-phenylbutan-2-yl hydroperoxide 
• 36238-13-8 [(2S)-3,3-dimethylbutan-2-yl]benzene 
• 19262-20-5 [(2R)-3,3-dimethylbutan-2-yl]benzene 
• 1312749-66-8 (R)-(3,3-dimethyl-1-nitrobutan-2-yl)benzene 
• 54321-15-2 (S)-3,3-Dimethyl-2-phenyl-1-butanol 
• 938-16-9 2,2-dimethylpropiophenone 
• 66444-08-4 1,1-dibromo-2-phenyl-2-tert-butylcyclopropane 
• 116076-85-8 5,5-dimethyl-4-phenyl-hexanenitrile 
• 19262-20-5 (1,2,2-Trimethyl-propyl)-benzene 
• 116076-86-9 1-cyclohexyl-3,3-dimethyl-2-phenylbutane 

Relevant articles and documents

METHOD FOR OXIDATIVE CLEAVAGE OF COMPOUNDS WITH UNSATURATED DOUBLE BOND

A method for oxidative cleavage of a compound with an unsaturated double bond is provided. The method includes the steps of: (A) providing a compound (I) with an unsaturated double bond, a trifluoromethyl-containing reagent, and a catalyst; wherein, the catalyst is represented by Formula (II): M(O)mL1yL2z??(II);wherein, M, L1, L2, m, y, z, R1, R2 and R3 are defined in the specification; and(B) mixing the compound with an unsaturated double bond and the trifluoromethyl-containing reagent to perform an oxidative cleavage of the compound with the unsaturated double bond by using the catalyst in air or under oxygen atmosphere condition to obtain a compound represented by Formula (III):

METHOD FOR OXIDATIVE CLEAVAGE OF COMPOUNDS WITH UNSATURATED DOUBLE BOND

A method for oxidative cleavage of a compound with an unsaturated double bond is provided. The method comprises the following step: (A) providing a compound (I) with an unsaturated double bond, a reagent with trifluoromethyl, and a catalyst; wherein the catalyst is represented by the following formula (II): M(O)mL1yL2z (II); wherein, M, L1, L2, m, y, z, R1, R2 and R3 are defined in the specification; and (B) mixing the compound with an unsaturated double bond and the reagent with a trifluoromethyl to perform an oxidation of the compound with the unsaturated double bond by using the catalyst at air or an oxygen condition to get a compound presented as formula (III):

Electron-deficient olefin ligands enable generation of quaternary carbons by Ni-catalyzed cross-coupling

A Ni-catalyzed Negishi cross-coupling with 1,1-disubstituted styrenyl aziridines has been developed. This method delivers valuable β-substituted phenethylamines via a challenging reductive elimination that affords a quaternary carbon. A novel electron-deficient olefin ligand, Fro-DO, proved crucial for achieving high rates and chemoselectivity for C-C bond formation over β-H elimination. This ligand is easy to access, is stable, and presents a modular framework for reaction discovery and optimization. We expect that these attributes, combined with the fact that the ligands impart distinct electronic properties to a metal, will support the invention of new transformations not previously possible using established ligands.