5676-29-9

Usage

Uses

Used in Polymer and Resin Production:
(1-tert-Butylvinyl)benzene is used as a monomer in the synthesis of various polymeric materials for its unique structure and reactivity. It plays a crucial role in the production of thermosetting plastics and elastomers, contributing to the development of materials with specific properties tailored for different applications.
Used in Material Science:
In the field of material science, (1-tert-Butylvinyl)benzene is utilized as a precursor in the synthesis of other valuable chemicals. Its involvement in chemical reactions allows for the creation of new compounds that can be applied across various industries, showcasing its versatility and importance in advancing material technologies.

InChI:InChI=1/C12H16/c1-10(12(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3

Upstream product

• 75-97-8 3,3-dimethyl-butan-2-one 
• 40920-10-3 2-tert-butyl-2-phenyl-thiirane 
• 2117-28-4 bis(trimethylsilyl)methane 
• 938-16-9 2,2-dimethylpropiophenone 
• 2371-91-7 2,3-dimethyl-3-phenylbutan-2-ol 
• 96-09-3 styrene oxide 
• 20667-19-0 methyltriphenylphosphonium iodide 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 42044-42-8 3,3-dimethyl-2-phenyl-2-butyl p-nitrobenzoate 
• 126179-52-0 1-benzoyl-2-tert-butyl-2-phenylaziridine 
• 22557-45-5 2,3-dimethyl-3-phenyl-1-butene 
• 594-19-4 tert.-butyl lithium 
• 536-74-3 phenylacetylene 
• 2065-66-9 methyl-triphenylphosphonium iodide 

Downstream Products

• 75732-44-4 4,5,5-trimethyl-4-phenyl-[1,2]oxathiolane-2,2-dioxide 
• 19262-20-5 (1,2,2-Trimethyl-propyl)-benzene 
• 116076-86-9 1-cyclohexyl-3,3-dimethyl-2-phenylbutane 
• 19262-20-5 [(2R)-3,3-dimethylbutan-2-yl]benzene 
• 116076-85-8 5,5-dimethyl-4-phenyl-hexanenitrile 
• 66444-08-4 1,1-dibromo-2-phenyl-2-tert-butylcyclopropane 
• 938-16-9 2,2-dimethylpropiophenone 
• 107847-16-5 (+/-)-2-(1,1-dimethylethyl)-2-phenyloxirane 
• 124-38-9 carbon dioxide 
• 98-86-2 acetophenone 
• 67-64-1 acetone 
• 36238-13-8 [(2S)-3,3-dimethylbutan-2-yl]benzene 
• 1312749-66-8 (R)-(3,3-dimethyl-1-nitrobutan-2-yl)benzene 
• 54321-15-2 (S)-3,3-Dimethyl-2-phenyl-1-butanol 

Relevant academic research and scientific papers

METHOD FOR OXIDATIVE CLEAVAGE OF COMPOUNDS WITH UNSATURATED DOUBLE BOND

A method for oxidative cleavage of a compound with an unsaturated double bond is provided. The method includes the steps of: (A) providing a compound (I) with an unsaturated double bond, a trifluoromethyl-containing reagent, and a catalyst; wherein, the catalyst is represented by Formula (II): M(O)mL1yL2z??(II);wherein, M, L1, L2, m, y, z, R1, R2 and R3 are defined in the specification; and(B) mixing the compound with an unsaturated double bond and the trifluoromethyl-containing reagent to perform an oxidative cleavage of the compound with the unsaturated double bond by using the catalyst in air or under oxygen atmosphere condition to obtain a compound represented by Formula (III):

Method for oxidative cracking of compound containing unsaturated double bonds

The invention relates to a method for oxidative cracking of a compound containing unsaturated double bonds. The method comprises the following steps: (A) providing a compound (I) containing unsaturated double bonds, a trifluoromethyl-containing reagent and a catalyst, wherein the catalyst is shown as a formula (II): M(O)mL1yL2z (II), M, L1, L2, m, y, z, R1, R2 and R3 being defined in the specification; and (B) mixing the compound containing the unsaturated double bonds and the trifluoromethyl-containing reagent, and performing an oxidative cracking reaction on the compound containing the unsaturated double bonds in the presence of air or oxygen by using the catalyst to obtain a compound represented by formula (III),.

METHOD FOR OXIDATIVE CLEAVAGE OF COMPOUNDS WITH UNSATURATED DOUBLE BOND

A method for oxidative cleavage of a compound with an unsaturated double bond is provided. The method comprises the following step: (A) providing a compound (I) with an unsaturated double bond, a reagent with trifluoromethyl, and a catalyst; wherein the catalyst is represented by the following formula (II): M(O)mL1yL2z (II); wherein, M, L1, L2, m, y, z, R1, R2 and R3 are defined in the specification; and (B) mixing the compound with an unsaturated double bond and the reagent with a trifluoromethyl to perform an oxidation of the compound with the unsaturated double bond by using the catalyst at air or an oxygen condition to get a compound presented as formula (III):

Visible light-promoted dihydroxylation of styrenes with water and dioxygen

An efficient visible light promoted metal-free dihydroxylation of styrenes with water and dioxygen has been developed for the construction of vicinal alcohols. The protocol was operationally simple with a broad substrate scope. The mechanistic studies demonstrated that one of the hydroxyl groups came from water and the other one came from molecular oxygen. Additionally, the β-alkyoxy alcohols could also be obtained using a similar strategy.

Electron-deficient olefin ligands enable generation of quaternary carbons by Ni-catalyzed cross-coupling

A Ni-catalyzed Negishi cross-coupling with 1,1-disubstituted styrenyl aziridines has been developed. This method delivers valuable β-substituted phenethylamines via a challenging reductive elimination that affords a quaternary carbon. A novel electron-deficient olefin ligand, Fro-DO, proved crucial for achieving high rates and chemoselectivity for C-C bond formation over β-H elimination. This ligand is easy to access, is stable, and presents a modular framework for reaction discovery and optimization. We expect that these attributes, combined with the fact that the ligands impart distinct electronic properties to a metal, will support the invention of new transformations not previously possible using established ligands.

Synergistic interplay of a non-heme iron catalyst and amino acid coligands in H2O2 activation for asymmetric epoxidation of α-alkyl-substituted styrenes

Highly enantioselective epoxidation of α-substituted styrenes with aqueous H2O2 is described by using a chiral iron complex as the catalyst and N-protected amino acids (AAs) as coligands. The amino acids synergistically cooperate with the iron center in promoting an efficient activation of H2O2 to catalyze epoxidation of this challenging class of substrates with good yields and stereoselectivities (up to 97% ee) in short reaction times.

Platinum(II) olefin hydroarylation catalysts: Tuning selectivity for the anti-Markovnikov product

PtII complexes containing unsymmetrical (pyri-dyl)pyrrolide ligands are shown to catalyze the hydroarylation of unactivated alkenes with selectivity for the anti-Markovnikov product. Substitution on the pyrrolide portion of the ligand allows effective tuning of the selectivity to anti-Markovnikov alkylarene products, whereas substitution on the pyridyl portion can promote competitive al-kenylarene production.

Chiral imidate-ferrocenylphosphanes: Synthesis and application as P,N-ligands in iridium(i)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

A small library of chiral imidate-ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium(i)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee's up to 100%).

Readily available hydrogen bond catalysts for the asymmetric transfer hydrogenation of nitroolefins

This paper focuses on readily accessible thiourea hydrogen bond catalysts derived from amino acids, whose steric and electronic features are modulated by their degree of substitution at the carbinol carbon center. These catalysts were applied in the asymmetric transfer hydrogenation of nitroolefins furnishing the chiral products in up to 99% yield and 86% enantiomeric excess. The proposed catalyst's mode of action is supported by mechanistic investigations.

Tandem insertion of halocarbenoids and lithium acetylides into zirconacycles: A novel rearrangement to zirconium alkenylidenates by β-addition to an alkynyl zirconocene

Tandem insertion of 1,1-dihalo-1-lithio species (halocarbenoids) and lithium alkynides into zirconacyclopentenes and zirconcyclopentanes affords carbocyclic products in high yields via an unusual rearrangement that probably involves addition of an organol