1923-01-9

Basic information

• Product Name: trimethyl-(1-phenylethenyl)silane
• Synonyms: trimethyl-(1-phenylethenyl)silane;(1-Phenylethenyl)trimethylsilane;[1-(Trimethylsilyl)vinyl]benzene;1-(Trimethylsilyl)-1-phenylethene;1-Trimethylsilylethenylbenzene;α-(Trimethylsilyl)styrene
• CAS NO: 1923-01-9
• Molecular Formula: C₁₁H₁₆Si
• Molecular Weight: 0
• Mol File: 1923-01-9.mol
• Article Data: 23

Chemical Properties

• Boiling Point: 217°Cat760mmHg
• Flash Point: 70.5°C
• Appearance: /
• Density: 0.864g/cm³
• Vapor Pressure: 0.199mmHg at 25°C
• Refractive Index: 1.484
• CAS DataBase Reference: trimethyl-(1-phenylethenyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: trimethyl-(1-phenylethenyl)silane(1923-01-9)
• EPA Substance Registry System: trimethyl-(1-phenylethenyl)silane(1923-01-9)

Safety Data

• Hazardous Substances Data: 1923-01-9(Hazardous Substances Data)

Usage

General Description

Trimethyl-(1-phenylethenyl)silane is a chemical compound with the molecular formula C11H16Si. It is a silicon-containing compound that is commonly used as a reagent in organic synthesis and as a precursor for various functionalized silicon compounds. This chemical is a colorless liquid with a molecular weight of 180.34 g/mol and a boiling point of 142-144°C. Trimethyl-(1-phenylethenyl)silane is insoluble in water but soluble in organic solvents such as ethanol and acetone. It is commonly used as a silylating agent in organic chemistry reactions to introduce silane groups into molecules.

InChI:InChI=1/C11H16Si/c1-10(12(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3

Upstream product

• 16029-98-4 trimethylsilyl iodide 
• 536-74-3 phenylacetylene 
• 18255-05-5 benzyl phenyl selenide 
• 56253-59-9 α-Trimethylsilylbenzyl Phenyl Selenid 
• 5908-41-8 benzoyltrimethylsilane 
• 917-64-6 methyl magnesium iodide 
• 13411-45-5 trimethyl(2-phenyl-1,3-dithian-2-yl)silane 
• 75-77-4 chloro-trimethyl-silane 
• 618-34-8 1-chlorostyrene 
• 13683-41-5 1-bromo-1-(trimethylsilyl)ethene 
• 100-58-3 phenylmagnesium bromide 
• 108-86-1 bromobenzene 
• 4545-21-5 acetophenone p-toluenesulfonylhydrazone 
• 49750-22-3 1-(trimethylsilyl)vinylmagnesium bromide 

Relevant articles and documents

1-(Trimethylsilyl)vinyl MIDA Boronate: A Trifunctional C 2 Building Block

1-(Trimethylsilyl)vinyl MIDA boronate - a trifunctional C 2 building block - is prepared in only two laboratory steps and 54% overall yield starting from readily available trimethyl(vinyl)silane. The title compound undergoes orthogonal functionalization at either of the groups present in its structure, for example, iodination at the trimethylsilyl moiety, epoxidation at the double bond, and Suzuki-Miyaura coupling at the MIDA boronate.

Preparation of Functionalized Acylsilanes by Diol Cleavage of Cyclic 1,2-Dihydroxysilanes

We report a study on diol cleavage of cyclic 1,2-dihydroxysilanes for the preparation of functionalized acylsilanes. Sodium periodate turned out to be an efficient reagent for this transformation, resulting in good to excellent yields. The method is chara

Preparation of Optically Active cis-Cyclopropane Carboxylates: Cyclopropanation of α-Silyl Stryenes with Aryldiazoacetates and Desilylation of the Resulting Silyl Cyclopropanes

Optically active cis-cyclopropane carboxylates are prepared via the Rh2(S-PTAD)4-catalyzed cyclopropanation of α-silyl styrenes with aryl diazoacetates followed by desilylation of the resulting silyl cyclopropane carboxylates. The co