56772-00-0Relevant articles and documents
Nickel-mediated decarbonylative cross-coupling of phthalimides with in situ generated diorganozinc reagents
Havlik, Sarah E.,Simmons, Jessica M.,Winton, Valerie J.,Johnson, Jeffrey B.
experimental part, p. 3588 - 3593 (2011/06/26)
The nickel-mediated cross-coupling of phthalimides with diorganozinc reagents proceeds via a decarbonylative process to produce ortho-substituted benzamides in high yields. In addition to tolerating diverse phthalimide functionality, including alkyl, aryl
One-pot double suzuki- miyaura couplings: Rapid access to nonsymmetrical tri(hetero)aryl derivatives
Beaumard, Floriane,Dauban, Philippe,Dodd, Robert H.
supporting information; experimental part, p. 1801 - 1804 (2009/08/15)
We describe a one-pot, simultaneous Suzuki- Miyaura cross-coupling of two different aryl boronic acids with symmetrical dibromo aryl and heterocyclic substrates to give as major products the unsymmetrical disubstituted tri(hetero)aryl derivatives. Yields
Pd/C-catalyzed deoxygenation of phenol derivatives using mg metal and MeOH in the presence of NH4OAc
Sajiki, Hironao,Mori, Akinori,Mizusaki, Tomoteru,Ikawa, Takashi,Maegawa, Tomohiro,Hirota, Kosaku
, p. 987 - 990 (2007/10/03)
A Pd/C-catalyzed deoxygenation method of phenolic hydroxyl groups via aryl triflates or mesylates using Mg metal in MeOH at room temperature was developed. The addition of NH4OAc dramatically affects the reactivity and reaction rate. This method is particularly attractive to provide an environmentally benign and widely applicable removal method of phenolic alcohols under quite mild reaction conditions.