56824-72-7Relevant academic research and scientific papers
Metal-Free Aerobic Oxidative Selective C-C Bond Cleavage in Heteroaryl-Containing Primary and Secondary Alcohols
Xia, Anjie,Qi, Xueyu,Mao, Xin,Wu, Xiaoai,Yang, Xin,Zhang, Rong,Xiang, Zhiyu,Lian, Zhong,Chen, Yingchun,Yang, Shengyong
supporting information, (2019/05/07)
A transition-metal-free aerobic oxidative selective C-C bond-cleavage reaction in primary and secondary heteroaryl alcohols is reported. This reaction was highly efficient and tolerated various heteroaryl alcohols, generating a carboxylic acid derivative and a neutral heteroaromatic compound. Experimental studies combined with density functional theory calculations revealed the mechanism underlying the selective C-C bond cleavage. This strategy also provides an alternative simple approach to carboxylation reaction.
Synthesis of 5-[(Acetylhydrazono)-(4-chlorophenyl)-methyl]thiophen-2-yl Ester of the Trifluoromethanesulfonic Acid
Pascual, Alfons
, p. 695 - 700 (2007/10/03)
The synthesis of 5-[(acetylhydrazono)-(4-chlorophenyl)-methyl]thiophen-2-yl ester of the trifluoromethanesulfonic acid (2a) and its N-methyl derivative 2b was attempted. Oxidation of 2-thiophene boronic acid to 2-hydroxythiophene and in situ reaction ther
