568592-11-0

Basic information

• Product Name: Benzenamine, 4-(2,7-dibromo-9H-carbazol-9-yl)-
• CAS NO: 568592-11-0
• Molecular Formula: C18H12Br2N2
• Molecular Weight: 416.115
• Mol File: 568592-11-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-(2,7-dibromo-9H-carbazol-9-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-(2,7-dibromo-9H-carbazol-9-yl)-(568592-11-0)
• EPA Substance Registry System: Benzenamine, 4-(2,7-dibromo-9H-carbazol-9-yl)-(568592-11-0)

Safety Data

• Hazardous Substances Data: 568592-11-0(Hazardous Substances Data)

Upstream product

• 350-46-9 4-Fluoronitrobenzene 
• 136630-39-2 2,7-dibromo-9H-carbazole 
• 540-37-4 p-aminoiodobenzene 
• 92-86-4 4-(4-bromophenyl)bromobenzene 
• 86-74-8 9H-carbazole 
• 568592-10-9 2,7-dibromo-9-(4-nitrophenyl)-9H-carbazole 

Downstream Products

• 1303532-42-4 N-(4-(2,7-di(1,3,2-dioxaborinan-2-yl)-9H-carbazol-9-yl)phenyl)-N-phenylbenzenamine 
• 1303991-86-7 2,7-di(1,3,2-dioxaborinan-2-yl)-9-phenyl-9H-carbazole 
• 444796-09-2 2,7-dibromo-9-(4-phenyl)-9H-carbazole 
• 1303532-40-2 N-(4-(2,7-dibromo-9H-carbazol-9-yl)phenyl)-N-phenylbenzenamine 
• 568592-16-5 dimethyl-{4-[7-(4-nitrophenylethynyl)-9-(4-trimethylsilanylethynylphenyl)-9H-carbazol-2-ylethynyl]phenyl}amine 
• 568592-17-6 {4-[9-(4-ethynylphenyl)-7-(4-nitrophenylethynyl)-9H-carbazol-2-ylethynyl]phenyl}dimethylamine 
• 568592-14-3 {4-[7-bromo-9-(4-trimethylsilanylethynylphenyl)-9H-carbazol-2-ylethynyl]phenyl}dimethylamine 
• 568592-15-4 {4-[7-iodo-9-(4-trimethylsilanylethynylphenyl)-9H-carbazol-2-ylethynyl]phenyl}dimethylamine 
• 568592-13-2 2,7-dibromo-9-(4-trimethylsilanylethynylphenyl)-9H-carbazole 
• 136630-39-2 2,7-dibromo-9H-carbazole 
• 568592-12-1 2,7-dibromo-9-(4-iodophenyl)-9H-carbazole 

Relevant articles and documents

Copolyfluorenes containing carbazole or triphenylamine and Diethoxylphosphoryl groups in the side chains as white-light-emitting polymers

New copolyfluorenes containing 4,7-di-2-thienyl-2,1,3-benzothiadiazole and 2,1,3-benzothiadiazole or derivatives of naphthalimide as luminophores were synthesized under microwave heating. Charge-transporting carbazole, triphenylamine, or diphenyloxadiazol

N-Arylation of carbazole by microwave-assisted ligand-free catalytic CuI reaction

N-Arylation of carbazole has been achieved in high yields within 1 h using a microwave-assisted catalytic CuI reaction with no organic ligand. The N-arylation can be performed by various arylhalides, such as phenyl, pyridine, thiophene, and thiazole moieties. Specifically, N-arylated bromocarbazoles were converted into useful synthetic intermediates for functionalized carbazole materials.

En route to surface-bound electric field-driven molecular motors

Four caltrop-shaped molecules that might be useful as surface-bound electric field-driven molecular motors have been synthesized. The caltrops are comprised of a pair of electron donor-acceptor arms and a tripod base. The molecular arms are based on a carbazole or oligo(phenylene ethynylene) core with a strong net dipole. The tripod base uses a silicon atom as its core. The legs of the tripod bear sulfur-tipped bonding units, as acetyl-protected benzylic thiols, for bonding to a gold surface. The geometry of the tripod base allows the caltrop to project upward from a metallic surface after self-assembly. Ellipsometric studies show that self-assembled monolayers of the caltrops are formed on Au surfaces with molecular thicknesses consistent with the desired upright-shaft arrangement. As a result, the zwitterionic molecular arms might be controllable when electric fields are applied around the caltrops, thereby constituting field-driven motors.