56957-56-3Relevant academic research and scientific papers
Synthesis of 1-organyl-1-(trimethylsiloxy)-2-(dimethylamino)ethenes and new hypervalent silicon compounds based thereon
Gostevskii,Albanov,Vashchenko,Smirnov
, p. 1385 - 1389 (2016/11/29)
1-Organyl-1-(trimethylsiloxy)-2-(dimethylamino)ethenes were synthesized for the first time, and their reactions with trichloro(methyl)silane and trifluoro(phenyl)silane afforded silicon bis-chelates, methylbis-[2-(dimethylamino)-1-(organyl)ethenolato-N,O]
Tandem catalytic allylic amination and [2,3]-stevens rearrangement of tertiary amines
Soheili, Arash,Tambar, Uttam K.
supporting information; experimental part, p. 12956 - 12959 (2011/10/08)
We have developed a catalytic allylic amination involving tertiary aminoesters and allylcarbonates, which is the first example of the use of tertiary amines as intermolecular nucleophiles in metal-catalyzed allylic substitution chemistry. This process is
