569646-48-6

Basic information

• Product Name: [2-(tert-butyl-diphenyl-silanyloxy)-5-methyl-benzyl]-dimethyl-amine
• Synonyms: [2-(tert-butyl-diphenyl-silanyloxy)-5-methyl-benzyl]-dimethyl-amine
• CAS NO: 569646-48-6
• Molecular Weight: 403.64
• Mol File: 569646-48-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [2-(tert-butyl-diphenyl-silanyloxy)-5-methyl-benzyl]-dimethyl-amine(CAS DataBase Reference)
• NIST Chemistry Reference: [2-(tert-butyl-diphenyl-silanyloxy)-5-methyl-benzyl]-dimethyl-amine(569646-48-6)
• EPA Substance Registry System: [2-(tert-butyl-diphenyl-silanyloxy)-5-methyl-benzyl]-dimethyl-amine(569646-48-6)

Safety Data

• Hazardous Substances Data: 569646-48-6(Hazardous Substances Data)

Upstream product

• 7204-35-5 2-(dimethylamino-methyl)-4-methyl-phenol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 21236-74-8 4-methyl-2-(piperidin-1-ylmethyl)phenol 
• 82807-53-2 4-methyl-2-(4-morpholinylmethyl)phenol 

Relevant articles and documents

Retro-Mannich reactions of 3-alkyl-3,4-dihydro-2H-1,3-benz[e]oxazines and the synthesis of axially chiral resorcinarenes

Intermediates involved in the conversion of 3-alkyl-3,4-dihydro-2H-1,3-benz[e]oxazines into 2-N,N-dialkylaminomethylphenol derivatives, using morpholine and other high boiling secondary amines, have been identified and characterised. Additional experiments have established the involvement of o-quinone methide intermediates in the retro-Mannich reactions. Axially chiral resorcinarenes have been prepared by utilising the exchange reactions.