569669-56-3

Upstream product

• 64030-44-0 (2S)-2-(anilinomethyl)pyrrolidine 

Downstream Products

• 1031399-78-6 3,6-bis[(2'R,5'S)-3'-phenyl-1',3'-diaza-2'-phosphabicyclo[3.3.0]octyloxy]-(3R,3aS,6R,6aS)-hexahydrofuro[3,2-b]furan 
• 1189024-72-3 (2R,5S)-2-(2',2',3',3',4',4',5',5',6',6',7',7',8',8',9',9',10',10',10'-nonadecafluorodecyloxy)-3-phenyl-1,3-diaza-2-phoshpabicyclo-[3.3.0]octane 
• 1228508-02-8 3-[(2R,5S)-3-phenyl-1,3-diaza-2-phosphabicyclo[3.3.0]oct-2-yloxy]-6-benzyloxy-(3R,3aS,6R,6aR)-hexahydrofuro[3,2-b]-furan 

Relevant academic research and scientific papers

P-chiral monodentate diamidophosphites - New and efficient ligands for palladium-catalysed asymmetric allylic substitution

Novel P*-monodentate diamidophosphite ligands have been prepared by a one-step phosphorylation of alcohols or amines. Both the electronic and the steric demands of the ligands have been estimated quantitatively. Neutral [Pd(allyl)Cl(L)] and cationic [Pd(a

New oxazoline-containing phosphoramidite ligand for palladium-catalyzed asymmetric allylic sulfonylation

New chiral oxazoline-containing phosphoramidite was synthesized and its complex formation with rhodium(I) and palladium(II) was examined. The new ligand is a highly efficient chiral inductor (ee up to 92%) in palladium-catalyzed asymmetric sulfonylation of 1,3-diphenylallyl acetate with sodium p-toluenesulfinate.

Chiral P*-monodentate phosphite ligand for Pd-catalysed asymmetric allylation reactions

Monodentate diamidophosphite ligand 2 with stereogenic phosphorus and carbon atoms, which is easily available from (S)-2-phenylaminomethyl pyrrolidine, is an effective chiral inductor in Pd-catalysed asymmetric allylation reactions.