570421-75-9Relevant academic research and scientific papers
The tert-butyl moiety - A base resistent thiol protecting group smoothly replaced by the labile acetyl moiety
Stuhr-Hansen, Nicolai
, p. 641 - 646 (2003)
Aryl t-butyl sulfides underwent quantitative tert-butyl/acetyl exchange reactions affording thioacetic acid S-aryl esters when treated with acetyl chloride and boron tribromide.
Utilization of microwave heating in the McMurry reaction for facile coupling of aldehydes and ketones to give alkenes
Stuhr-Hansen, Nicolai
, p. 5491 - 5494 (2007/10/03)
Microwave heating was applied in high-yield syntheses of alkenes by McMurry coupling of aldehydes and ketones with low-valent titanium. All aldehydes and ketones including sulfur end-capped analogues gave alkenes in isolated yields above 80% without detectable amounts of pinacols.
