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Magnesium, chloro[4-(ethoxycarbonyl)phenyl]- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 571903-64-5 Structure
  • Basic information

    1. Product Name: Magnesium, chloro[4-(ethoxycarbonyl)phenyl]-
    2. Synonyms:
    3. CAS NO:571903-64-5
    4. Molecular Formula: C9H9ClMgO2
    5. Molecular Weight: 208.927
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 571903-64-5.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Magnesium, chloro[4-(ethoxycarbonyl)phenyl]-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Magnesium, chloro[4-(ethoxycarbonyl)phenyl]-(571903-64-5)
    11. EPA Substance Registry System: Magnesium, chloro[4-(ethoxycarbonyl)phenyl]-(571903-64-5)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 571903-64-5(Hazardous Substances Data)

571903-64-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 571903-64-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 5,7,1,9,0 and 3 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 571903-64:
(8*5)+(7*7)+(6*1)+(5*9)+(4*0)+(3*3)+(2*6)+(1*4)=165
165 % 10 = 5
So 571903-64-5 is a valid CAS Registry Number.

571903-64-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-(ethoxycarbonyl)phenylmagnesium chloride

1.2 Other means of identification

Product number -
Other names 4-carbethoxyphenylmagnesium chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:571903-64-5 SDS

571903-64-5Relevant articles and documents

Sequential nucleophilic addition/1,2-rearrangement of N-iminolactam: A ring-contractive strategy for the synthesis of 2-acyl pyrrolidines

Kido, Yusaku,Kobori, Yukiko,Matsumoto, Yuki,Orihara, Kotomi,Takeda, Norihiko,Ueda, Masafumi,Yasui, Motohiro

supporting information, (2021/06/07)

A sequential nucleophilic addition/ring contraction of α-bromo N-iminolactam with organometallic reagents for the synthesis of 2-acyl pyrrolidines has been developed. The reaction allows facial construction of 2-acyl pyrrolidines incorporating not only ar

Iron-Catalyzed Room Temperature Cross-Couplings of Bromophenols with Aryl Grignard Reagents

Xu, Li-Chen,Liu, Kun-Ming,Duan, Xin-Fang

, p. 5421 - 5427 (2019/11/14)

Herein we report a room temperature Fe-catalyzed coupling reaction of various bromophenols with aryl Grignard reagents, which exhibits a wide substrate scope and high functional group tolerance. For the first time, the combination of simple Fe(acac)3/PBu3/Ti(OEt)4 has been used as an effective catalyst for the biaryl couplings of bromophenols or their Na or K salts with debromination and etherification side reactions being well suppressed. Various biphenols including natural product garcibiphenyl C as well as pharmaceutical diflunisal and its ethyl ester were facilely synthesized using the present protocol. (Figure presented.).

Cobalt-catalyzed addition of arylzinc reagents to alkynes to form ortho-alkenylarylzinc species through 1,4-cobalt migration

Tan, Boon-Hong,Dong, Jinghua,Yoshikai, Naohiko

supporting information, p. 9610 - 9614 (2012/11/07)

Migratory carbometalation: A cobalt-Xantphos complex catalyzes the addition of an arylzinc reagent to an unactivated internal alkyne; the reaction most likely involves insertion of the alkyne into an arylcobalt species and vinyl-to-aryl 1,4-cobalt migration, followed by transmetalation with the arylzinc reagent. Interception of the resulting ortho-alkenylarylzinc species with electrophiles allows access to 1-alkenyl arenes functionalized in the 2-position. Copyright

Radical catalysis of kumada cross-coupling reactions using functionalized grignard reagents

Manolikakes, Georg,Knochel, Paul

supporting information; experimental part, p. 205 - 209 (2009/04/10)

(Chemical Equation Presented) Palladium, radically different: A wide range of polyfunctional aryl- and heteroarylmagnesium reagents undergo fast Kumada cross-couplings (see scheme) with functionalized aryl bromides in the presence of a palladium catalyst and an alkyl iodide as additive. These reactions proceed by a radical pathway.

Iron-catalyzed aryl-aryl cross-couplings with magnesium-derived copper reagents

Sapountzis, Ioannis,Lin, Wenwei,Kofink, Christiane C.,Despotopoulou, Christina,Knochel, Paul

, p. 1654 - 1657 (2007/10/03)

(Chemical Equation Presented) Well-matched couples: Functionalized aryl and heteroaryl copper species obtained from the corresponding magnesium derivatives undergo Fe-catalyzed cross-coupling reactions with aryl iodides that bear keto, ester, triflate, or nitrile groups (see scheme).

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