959141-01-6

Basic information

• Product Name: 4-cyclohexyl-benzoic acid ethyl ester
• Synonyms: 4-cyclohexyl-benzoic acid ethyl ester
• CAS NO: 959141-01-6
• Molecular Weight: 232.323
• Mol File: 959141-01-6.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: 4-cyclohexyl-benzoic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-cyclohexyl-benzoic acid ethyl ester(959141-01-6)
• EPA Substance Registry System: 4-cyclohexyl-benzoic acid ethyl ester(959141-01-6)

Safety Data

• Hazardous Substances Data: 959141-01-6(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 20029-52-1 4-cyclohexylbenzoic acid 
• 51934-41-9 4-iodobenzoic acid ethyl ester 
• 931-50-0 cyclohexylmagnesium bromide 
• 5798-75-4 Ethyl 4-bromobenzoate 
• 15658-08-9 dicyclohexylzinc(II) 
• 626-62-0 Cyclohexyl iodide 
• 451-46-7 4-fluorobenzoic acid ethyl ester 
• 135303-54-7 (Cy)Ti(O-i-Pr)3 
• 931-51-1 cyclohexylmagnesiumchloride 
• 108-85-0 1-bromocyclohexane 
• 124915-06-6 ethyl 4-(N,N,N-trimethylammonium)-1-benzoate triflate 
• 571903-64-5 4-(ethoxycarbonyl)phenylmagnesium chloride 
• 256390-55-3 cyclohexylzinc chloride 

Downstream Products

• 1186633-78-2 5-(4-(5-(4-(4-cyclohexylbenzyloxy)benzylidene)-3-methyl-4-oxothiazolidin-2-ylideneamino)phenyl)-1,1-dioxo-1λ6-[1,2,5]thiadiazolidin-3-one 
• 1186634-20-7 N-(4-(5-(4-(4-cyclohexylbenzyloxy)benzylidene)-3-methyl-4-oxothiazolidin-2-ylideneamino)phenyl)oxalamic acid ethyl ester 
• 1186633-83-9 N-(4-(5-(4-(4-cyclohexylbenzyloxy)benzylidene)-3-methyl-4-oxothiazolidin-2-ylideneamino)phenyl)oxalamic acid 
• 1186634-15-0 (4-(5-(1-(4-(4-cyclohexylbenzyloxy)phenyl)methylidene)-3-methyl-4-oxothiazolidin-2-ylideneamino)phenyl)fluoroacetic acid ethyl ester 
• 1186634-13-8 (4-(5-(1-(4-(4-cyclohexylbenzyloxy)phenyl)methylidene)-3-methyl-4-oxothiazolidin-2-ylideneamino)phenyl)hydroxyacetic acid ethyl ester 
• 1186633-91-9 (4-(5-(1-(4-(4-cyclohexylbenzyloxy)phenyl)methylidene)-3-methyl-4-oxothiazolidin-2-ylideneamino)phenyl)hydroxyacetic acid 
• 1186633-86-2 (4-(5-(4-(4-cyclohexylbenzyloxy)benzylidene)-3-methyl-4-oxothiazolidin-2-ylideneamino)phenyl)oxoacetic acid 
• 1186633-85-1 (4-(5-(1-(4-(4-cyclohexylbenzyloxy)phenyl)methylidene)-3-methyl-4-oxothiazolidin-2-ylideneamino)phenyl)fluoroacetic acid 
• 1186634-17-2 2-(4-acetylphenylimino)-5-(4-(4-cyclohexylbenzyloxy)benzylidene)-3-methylthiazolidin-4-one 
• 1186634-19-4 2-(4-aminophenylimino)-5-(4-(4-cyclohexylbenzyloxy)benzylidene)-3-methylthiazolidin-4-one 
• 1186634-18-3 5-(4-(4-cyclohexylbenzyloxy)benzylidene)-3-methyl-2-(4-nitrophenyimino)thiazolidin-4-one 
• 1186634-26-3 4-(4-cyclohexylbenzyloxy)benzaldehyde 
• 4463-31-4 4-cyclohexylbenzyl chloride 
• 861097-02-1 Hydroxy-bis-(3-cyclohexyl-phenyl)-(4-cyclohexyl-phenyl)-methan 

Relevant articles and documents

Micelle enabled C(sp2)-C(sp3) cross-electrophile coupling in waterviasynergistic nickel and copper catalysis

A robust and sustainable C(sp2)-C(sp3) cross-electrophile coupling was developedvianickel/copper synergistic catalysis under micellar conditions. This protocol provided a general method to access alkylated arenes with good to excellent yields on a very large scale.

General C(sp2)-C(sp3) Cross-Electrophile Coupling Reactions Enabled by Overcharge Protection of Homogeneous Electrocatalysts

Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction can readily exceed the reducing potentials of chemical reductants to activate catalysts with improved reactivities and selectivities over conventional systems. This work details the mechanistically-driven development of an electrochemical methodology for XEC that utilizes redox-active shuttles developed by the energy-storage community to protect reactive coupling catalysts from overreduction. The resulting electrocatalytic system is practical, scalable, and broadly applicable to the reductive coupling of a wide range of aryl, heteroaryl, or vinyl bromides with primary or secondary alkyl bromides. The impact of overcharge protection as a strategy for electrosynthetic methodologies is underscored by the dramatic differences in yields from coupling reactions with added redox shuttles (generally >80%) and those without (generally 20%). In addition to excellent yields for a wide range of substrates, reactions protected from overreduction can be performed at high currents and on multigram scales.

Iron-catalyzed cross-coupling of aryltrimethylammonium triflates and alkyl Grignard reagents

Fe(acac)3 effectively catalyzes reaction of aryltrimethylammonium triflates with β-hydrogen-containing primary or secondary alkyl Grignard reagents in a mixed solvent of THF and NMP at room temperature. A series of functional groups are tolerated under the reaction conditions.