57203-50-6Relevant academic research and scientific papers
GROUP 5 METAL COMPLEXES FOR PRODUCING AMINE-FUNTIONALIZED POLYOLEFINS
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Page/Page column 64, (2019/12/15)
This application pertains to group 5 metal complexes having the structure of Formula I: and their potential utility in catalyzing amination of polyolefins having alkene groups.amine-
Conventional and tandem hydroformylation
Vasylyev, Maksym,Alper, Howard
scheme or table, p. 2893 - 2900 (2010/10/21)
Transition-metal-catalyzed hydroformylation has become an essential tool for the synthesis of aldehydes. In this paper, we highlight several examples of synthetically useful applications of homogeneous and heterogeneous rhodium-catalyzed hydroformylation, as well as several examples of tandem processes involving hydroformylation as a reaction step developed in our laboratory.
Synthesis of secondary amines by reduction of α-amidoalkylphenyl sulfones with sodium acetoxyborohydride
Mataloni, Michela,Petrini, Marino,Profeta, Roberto
, p. 1129 - 1132 (2007/10/03)
α-Amidoalkylphenyl sulfones are stable precursors of reactive N-acylimines and can be fully reduced to the corresponding secondary amines using sodium acetoxyborohydride in dioxane at reflux.
Zwitterionic rhodium complex catalyzed hydroaminomethylation of arylethylenes
Lin, Yong-Shou,El Ali, Bassam,Alper, Howard
, p. 2423 - 2425 (2007/10/03)
The hydroaminomethylation of arylethylenes can be achieved in high regioselectivity using the zwitterionic rhodium complex [Rh+(cod)(η6-PhBPh3)-] (1) as the catalyst under relatively mild conditions.
Synthesis of β-phenylethylamines from styrene derivatives
Seijas, Julio A.,Vazquez-Tato, M. Pilar,Entenza, Cesar,Martinez, M. Montserrat,Onega, M. Gabriela,Veiga, Susana
, p. 5073 - 5076 (2007/10/03)
β-Phenylethylamines are prepared from the styrene derivatives; 4,4- dimethyl-2-(2-vinylphenyl)-2-oxazoline, 2-(3-methoxy-2-vinylpnenyl)-4,4- dimethyl-2-oxazoline, 2-vinylbenzoic acid, styrene, β-methylstyrene, and α- methylstyrene.
