5723-95-5Relevant academic research and scientific papers
Secondary isotope effects on the deslipping reaction of rotaxanes: High-precision measurement of steric size
Felder, Thorsten,Schalley, Christoph A.
, p. 2258 - 2260 (2007/10/03)
A supramolecular measuring instrument for determining steric size: The deslipping reaction of the rotaxane shown with deuterated stopper groups senses the smaller steric size of the deuterium atom and proceeds with a 10% higher reaction rate than the reaction of the unlabeled rotaxane. This result sheds new light from a supramolecular point of view on the classical problem of determining steric demand.
Solid state acetylation with acetylimidazole: Selective protection of primary alcohols and phenols
Hagiwara, Hisahiro,Morohashi, Kimie,Suzuki, Toshio,Ando, Masayoshi,Yamamoto, Isao,Kato, Michiharu
, p. 2001 - 2006 (2007/10/03)
Primary alcohols and phenols have been acetylated with acetylimidazole by the solid state reaction, grinding both substrates with a pestle in a mortar.
