57232-69-6Relevant academic research and scientific papers
Asymmetric spirocyclization: A new type of acid-catalyzed intramolecular 1,4-addition to form carba-spirocyclic compounds
Yamada, Satoshi,Karasawa, Satoru,Takahashi, Youichi,Aso, Mariko,Suemune, Hiroshi
, p. 15555 - 15566 (2007/10/03)
Novel spirocyclization based on intramolecular 1,4-addition and its asymmetric version have been developed using a combination of Lewis acid and 1,2-diol. Treatment of five- and six-membered α,β-unsaturated cyclic ketones having a 4-oxopentyl group at the
1-Benzyl-2,6-dicyanopiperidines as a New Class of Annelating Reagents. Use for Preparation of Fused Polycyclic Compounds
Takahashi, Kazumasa,Asakawa, Mikio,Ogura, Katsuyuki
, p. 1109 - 1112 (2007/10/02)
The utility of 1-benzyl-2,6-dialkyl-2,6-dicyanopiperidines as an annelating reagent, i.e. latent 1,5-diketones, is demonstrated in synthesis of multi-fused compounds.
