57241-98-2Relevant academic research and scientific papers
Synthesis and coordination chemistry of perfluoroalkyl-derivatised β-diketonates
Croxtal, Ben,Fawcett, John,Hope, Eric G.
, p. 65 - 73 (2007/10/03)
A series of fluorinated β-diketones, RfC(O)CH2C(O)Rf′ (Rf = C6F13, Rf′ = CF3; Rf = Rf′ = C6F13, C7F15), have been prepared in reasonable yields by a two-step synthesis. On reaction with appropriate metal substrates deprotonation and concurrent coordination of the perfluoroalkyl-derivatised β-diketonate ligands affords a range of fluorous metal complexes which have been characterised by elemental analysis, mas spectrometry, IR and NMR spectroscopies. The structures of [Cu(L-L)2(H2O)2] {L-L = CF3C(O)CHC(O)C6F13, C6F13C(O)CHC(O)C6F13}.
