57476-59-2Relevant articles and documents
2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4,6-diphenylpyridine: Synthesis and characterization of novel Cr0, Mo0 and W0 carbonyl complexes containing chelating P,N and N,N ligands
De Krom, Iris,Lutz, Martin,Müller, Christian
, p. 10304 - 10314 (2015/06/08)
Replacing nitrogen by phosphorus in otherwise similar structures changes the properties of the resulting compounds significantly due to the electronic differences that exist between these heteroatoms. While the "hard" nitrogen atom of the pyridine moiety
Preparation and Reactions of Pyrylium Salts containing α-Pyridyl Groups
Katritzky, Alan R.,Elisseou, E. Michael,Patel, Ranjan C.,Plau, Bernard
, p. 125 - 130 (2007/10/02)
The preparation of unsymmetrical 2,4,6-trisubstituted pyrylium salts from αβ-unsaturated ketones and methyl ketones is complicated by retro-aldol reactions leading to corresponding symmetrical pyrylium salts. 4,6-Diphenyl-2-(1H-pyridinium-2-yl)pyrylium (5a) and (5b) is prepared successfully by oxidation of the 1,5-dione from chalcone and 2-acetylpyridine.The transformation of pyrylium into pyridinium occurs easily with primary amines to 2-(2-pyridyl)pyridiniums whose various reactions are studied.