5757-83-5Relevant academic research and scientific papers
Synthesis of isoquinolines via Rh(III)-catalyzed C-H activation using hydrazone as a new oxidizing directing group
Chuang, Sheng-Chieh,Gandeepan, Parthasarathy,Cheng, Chien-Hong
supporting information, p. 5750 - 5753 (2013/12/04)
An efficient and mechanistically interesting method for the synthesis of highly substituted isoquinolines by a Rh(III)-catalyzed hydrazone directed ortho C-H bond activation and annulation without an external oxidant is described. This reaction is accomplished via a C-C and C-N bond formation along with N-N bond cleavage.
Highly efficient Narasaka-Heck cyclizations mediated by P(3,5-(CF 3)2C6H3)3: Facile access to N-heterobicyclic scaffolds
Faulkner, Adele,Bower, John F.
supporting information; experimental part, p. 1675 - 1679 (2012/04/05)
N-heterobicyclic scaffolds: Highly efficient palladium-catalyzed cyclizations of oxime esters with cyclic alkenes were used as a general entry to perhydroindole and related scaffolds. The chemistry is reliant upon the use of P(3,5-(CF3)2/
