57586-92-2

Basic information

• Product Name: (E)-tetrahydro-2-(11-tetradecenyloxy)-2H-pyran
• Synonyms: (E)-tetrahydro-2-(11-tetradecenyloxy)-2H-pyran;2H-Pyran, tetrahydro-2-((11E)-11-tetradecenyloxy)-;Tetrahydro-2-[(E)-11-tetradecenyloxy]-2H-pyran;(E)-2-((11-Tetradecenyl)oxy)tetrahydro-2H-pyran;2H-Pyran, tetrahydro-2-((11E)-11-tetradecen-1-yloxy)-;2H-Pyran, tetrahydro-2-(11-tetradecenyloxy)-, (E)-;Einecs 260-836-9
• CAS NO: 57586-92-2
• Molecular Formula: C₁₉H₃₆O₂
• Molecular Weight: 296.48794
• EINECS: 260-836-9
• Mol File: 57586-92-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 382.1°Cat760mmHg
• Flash Point: 122.3°C
• Appearance: /
• Density: 0.9g/cm³
• Vapor Pressure: 1.06E-05mmHg at 25°C
• Refractive Index: 1.467
• CAS DataBase Reference: (E)-tetrahydro-2-(11-tetradecenyloxy)-2H-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-tetrahydro-2-(11-tetradecenyloxy)-2H-pyran(57586-92-2)
• EPA Substance Registry System: (E)-tetrahydro-2-(11-tetradecenyloxy)-2H-pyran(57586-92-2)

Safety Data

• Hazardous Substances Data: 57586-92-2(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthetic Communications, 14, p. 179, 1984 DOI: 10.1080/00397918408062821

InChI:InChI=1/C19H36O2/c1-2-3-4-5-6-7-8-9-10-11-12-14-17-20-19-16-13-15-18-21-19/h3-4,19H,2,5-18H2,1H3/b4-3+

Upstream product

• 50816-20-1 2-(8-bromooctyloxy)tetrahydropyran 
• 63281-96-9 (E)-1-bromo-3-hexene 
• 7611-87-2 1(E)-chloro-1-butene 
• 917-54-4 methyllithium 
• 76063-05-3 1-mesyloxy-13-tetrahydropyranyloxy-2(E)-tridecene 
• 57586-82-0 [1-((E)-Propenyl)-11-(tetrahydro-pyran-2-yloxy)-undecyl]-phosphonic acid diethyl ester 
• 1577-18-0 (E)-3-hexenoic acid 
• 928-97-2 (E)-3-hexen-1-ol 
• 69157-16-0 3(E)-hexenoic-ethanoic anhydride 
• 51795-88-1 1-bromo-10-(tetrahydropyranyloxy)decane 
• 112-43-6 10-Undecen-1-ol 
• 692-86-4 ethyl 10-undecenenoate 
• 38067-98-0 11-(Tetrahydro-2H-pyran-2-yloxy)undecan-1-ol 
• 76070-19-4 11-((tetrahydro-2H-pyran-2-yl)oxy)undecanal 

Downstream Products

• 33189-72-9 (E)-tetradec-11-en-1-yl acetate 
• 35746-21-5 E,Z-11-tetradecen-1-al 
• 35153-18-5 (E)-11-tetradecen-1-ol 

Relevant articles and documents

Stereoselective synthesis of 11(E)-tetradecen-1-yl acetate-Sex pheromone of sod webworm (Loxostege sticticalis)

On the basic of Claisen rearrangement using orthoesters we carried out stereoselective synthesis of 11(E)-tetradecen-1-yl acetate, a sex pheromone of sod webworm (Loxostege sticticalis), which is a specially dangerous pests of crops.

SYNTHESIS OF(E) AND (Z) ALKENES VIA PALLADIUM OR NICKEL-CATALYZED REACTION OF VINYL CHLORIDES WITH GRIGNARD REAGENTS.

We herein described (i) a useful transformation of (E) and (Z) vinyl chlorides into E (and Z) olefins and (ii) an efficient preparation of monoenic alcohols or acetates and its application to insect pheromones.

Pheromones XXVIII. A stereoselective synthesis of (E)-olefinic sex pheromones of moths

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