1577-18-0Relevant articles and documents
Stereoselective catalytic hydrogenation of sorbic acid and sorbic alcohol with new Cp*Ru complexes
Steines, Stephan,Englert, Ulli,Driessen-Hoelscher, Birgit
, p. 217 - 218 (2000)
The new Cp*Ru complexes [Cp*Ru(η4-MeCH=CHCH=CHCO2H)]+X- (X- = CF3SO3- or [B{C6H3(CF3)2-3,5}4]-) are very effective catalysts for the hydrogenation of sorbic acid to cis-hex-3-enoic acid and of sorbic alcohol to cis-hex-3-en-1-ol (leaf alcohol) under mild conditions in liquid two-phase systems.
Palladium-Catalyzed Amide-Directed Enantioselective Hydrocarbofunctionalization of Unactivated Alkenes Using a Chiral Monodentate Oxazoline Ligand
Wang, Hao,Bai, Zibo,Jiao, Tangqian,Deng, Zhiqiang,Tong, Huarong,He, Gang,Peng, Qian,Chen, Gong
supporting information, p. 3542 - 3546 (2018/03/21)
A Pd-catalyzed amide-directed enantioselective hydrocarbofunctionalization of unactivated alkenes with C-H nucleophiles has been developed using a chiral monodentate oxazoline (MOXin) ligand. Various indoles react at C3 position with aminoquinoline-coupled 3-alkenamides to give γ addition products in good to excellent yield and enantioselectivity. This study represents an important advance of the development of chiral monodentate oxazoline ligands, which have been underexplored for asymmetric catalysis.
Regioselective ring opening and isomerization reactions of 3,4-epoxyesters catalyzed by boron trifluoride
Izquierdo, Javier,Rodriguez, Santiago,Gonzalez, Florenci V.
supporting information; experimental part, p. 3856 - 3859 (2011/09/19)
Efficient ring opening of 3,4-epoxyesters with alcohols to produce 4-alkoxy-3-hydroxyesters and their isomerization into 4-ketoesters using boron trifluoride as the catalyst are presented. Both transformations are simple and efficient methods for the synthesis of the above named synthetically useful compounds.
